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Surfactant-Assisted Synthesis of α-Fe2O3 Nanotubes and Nanorods with Shape-Dependent Magnetic Properties
Abstract
Alpha-Fe(2)O(3) nanorods and nanotubes have been synthesized and characterized by high-resolution transmission electron microscopy and X-ray diffraction. By means of different surfactant assistance, the high-quality one-dimensional products were obtained, respectively, with aqueous butanol solution as the solvent and carbamide as the base, giving rise to single-crystalline products at 150 degrees C. The formation mechanism has been presented. Significantly, the magnetic investigations show that the magnetic properties are strongly shape-dependent; i.e., the nanorods have a Morin transition at 166 K from canted antiferromagnetic state to antiferromagnetic state, while the nanotubes exhibit a three-dimensional magnetic ordering above 300 K that has been attributed to the presence of small particles in a few regions of the tubes.
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Cites
Perspectives on the Physical Chemistry of Semiconductor Nanocrystals
Alivisatos, A. P. (1996) · The Journal of Physical Chemistry · doi:10.1021/jp9535506 · Cited by 3,595
Cited by
Hierarchical α-Fe2O3/NiO Composites with a Hollow Structure for a Gas Sensor
Wang, C., Cheng, X., Zhou, X., Sun, P., Hu, X., Shimanoe, K., Lu, G., & Yamazoe, N. (2014) · ACS Applied Materials & Interfaces · doi:10.1021/am501063z · Cited by 283
Metadata
- Authors
- Liu, L., Kou, H.-Z., Mo, W., Liu, H., & Wang, Y.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-07-19
- Volume
- 110
- Issue
- 31
- Pages
- 15218-15223
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2058979620
- Cited by
- 245
- References
- 1
- FWCI
- 14.58
- Type
- journal article
- Language
- en
- Open access
- closed
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- Liu, L., Kou, H.-Z., Mo, W., Liu, H., & Wang, Y. (2006). Surfactant-Assisted Synthesis of α-Fe2O3 Nanotubes and Nanorods with Shape-Dependent Magnetic Properties. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp0627473
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