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Fast Electron Transport in Metal Organic Vapor Deposition Grown Dye-sensitized ZnO Nanorod Solar Cells
Open accessAbstract
The electron transport in dye-sensitized solar cells with a MOCVD (metal organic vapor deposition)-grown ZnO nanorod array (ZnO-N) or a mesoporous film prepared from ZnO colloids (ZnO-C) as the working electrode was compared. The electrodes were of similar thickness (2 mum) and sensitized with zinc(II) meso-tetrakis(3-carboxyphenyl)porphyrin, while the electrolyte was I(-)/I(3)(-) in 3-methoxypropionitrile. Electron transport in the ZnO-C cells was comparable with that found for colloidal TiO(2) films (transport time approximately 10 ms) and was light intensity dependent. Electron transport in solar cells with ZnO-N electrodes was about 2 orders of magnitude faster ( approximately 30 mus). Thus, the morphology of the working ZnO electrode plays a key role for the electron transport properties.
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Cited by
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Metadata
- Authors
- Galoppini, E., Rochford, J., Chen, H., Saraf, G., Lu, Y., Hagfeldt, A., & Boschloo, G.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-08-01
- Volume
- 110
- Issue
- 33
- Pages
- 16159-16161
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2024320624
- Cited by
- 429
- References
- 0
- FWCI
- 23.28
- Type
- journal article
- Language
- en
- Open access
- green
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