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Applications for Metal−Organic Frameworks (MOFs) as Quantum Dot Semiconductors
Abstract
The structure of MOF-5 is considered as being constructed of discrete semiconductor Zn 4 O 13 quantum dots stabilized and interconnected by terephthalate linkers. Terephthalate can absorb light and sensitize the semiconductor dots. In this way, MOFs exhibit the photocatalytic activity of MOF-5 for the degradation of phenols. As a photocatalyst, the most remarkable feature of MOF-5 is the observation of reverse shape-selectivity in which large phenolic molecules that cannot access the interior of the micropores are degraded significantly faster than those others that can enter into the particle. MOF-5 also exhibits activity as an active component in photovoltaic and electroluminescence cells.
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Citations
Cited by
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Kubacka, A., Fernández-García, M., & Colón, G. (2012) · Chemical Reviews · doi:10.1021/cr100454n · Cited by 2,373
Metal–organic frameworks as platforms for clean energy
Li, S.-L., & Xu, Q. (2013) · Energy & Environmental Science · doi:10.1039/c3ee40507a · Cited by 970
Photocatalytic Cr(VI) reduction in metal-organic frameworks: A mini-review
Wang, C.-C., Du, X.-D., Li, J., Guo, X.-X., Wang, P., & Zhang, J. (2016) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2016.04.030 · Cited by 659
MOFs as catalysts: Activity, reusability and shape-selectivity of a Pd-containing MOF
LLABRESIXAMENA, F., ABAD, A., CORMA, A., & GARCIA, H. (2007) · Journal of Catalysis · doi:10.1016/j.jcat.2007.06.004 · Cited by 549
Self-citationModified metal-organic frameworks as photocatalysts
Qiu, J., Zhang, X., Feng, Y., Zhang, X., Wang, H., & Yao, J. (2018) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2018.03.039 · Cited by 499
Manufacture of dense coatings of Cu3(BTC)2 (HKUST-1) on α-alumina
Gascon, J., Aguado, S., & Kapteijn, F. (2008) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2007.11.014 · Cited by 334
Metadata
- Authors
- Llabrés i Xamena, F. X., Corma, A., & Garcia, H.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-12-06
- Volume
- 111
- Issue
- 1
- Pages
- 80-85
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2093868903
- Cited by
- 402
- References
- 0
- FWCI
- 5.67
- Type
- journal article
- Language
- en
- Open access
- closed
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