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Color-Tunable, Aggregation-Induced Emission of a Butterfly-Shaped Molecule Comprising a Pyran Skeleton and Two Cholesteryl Wings

Tong, Hui, Hong, Yuning, Dong, Yongqiang, Ren, Yan, Häussler, Matthias, Lam, Jacky W. Y., Wong, Kam Sing, Tang, Ben Zhong·2007·The Journal of Physical Chemistry B

Abstract

A chiral pyran derivative containing two cholesteryl groups (1) is synthesized, and its optical properties are investigated. Whereas the isolated molecule of 1 is virtually nonluminescent in dilute solutions, it becomes highly emissive with a 2 orders of magnitude increase in fluorescence quantum yield upon aggregation in poor solvents or in solid state, showing a novel phenomenon of aggregation-induced emission (AIE). The color and efficiency of the AIE of 1 can be tuned by varying the morphology of its aggregates: photoluminescence of its aggregates formed in a tetrahydrofuran/water mixture progressively red-shifts (green --> yellow --> red) with increasing water content of the mixture, with the crystalline aggregates emitting bluer lights in higher efficiencies than their amorphous counterparts.

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Metadata

Authors
Tong, H., Hong, Y., Dong, Y., Ren, Y., Häussler, M., Lam, J. W. Y., Wong, K. S., & Tang, B. Z.
Venue
The Journal of Physical Chemistry B
Published
2007-02-02
Volume
111
Issue
8
Pages
2000-2007
ISSN
  • 1520-5207 (ISSN-L)
  • 1520-6106
OpenAlex
W2009797518
Cited by
233
References
0
FWCI
8.04
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Color-Tunable, Aggregation-Induced Emission of a Butterfly-Shaped Molecule Comprising a Pyran Skeleton and Two Cholesteryl Wings. https://app.cochat.ai/papers/10.1021/jp067374k
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Tong, H., Hong, Y., Dong, Y., Ren, Y., Häussler, M., Lam, J. W. Y., Wong, K. S., & Tang, B. Z. (2007). Color-Tunable, Aggregation-Induced Emission of a Butterfly-Shaped Molecule Comprising a Pyran Skeleton and Two Cholesteryl Wings. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp067374k

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