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Nanoscale Segregation in Room Temperature Ionic Liquids
Abstract
Room-temperature ionic liquids (RTILs) are organic salts that are characterized by low melting points. They are considered to possess a homogeneous microscopic structure. We provide the first experimental evidence of the existence of nanoscale heterogeneities in neat liquid and supercooled RTILs, such as 1-alkyl-3-methyl imidazolium-based salts, using X-ray diffraction. These heterogeneities are of the order of a few nanometers and their size is proportional to the alkyl chain length. These results provide strong support to the findings from recent molecular dynamics simulations, which proposed the occurrence of nanostructures in RTILs, as a consequence of alkyl chains segregation. Moreover, our study addresses the issue of the temperature dependence of the heterogeneities size, showing a behavior that resembles the density one only below the glass transition, thus suggesting a complex behavior above this temperature. These results will provide a novel interpretation approach for the unique chemical physical properties of RTILs.
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Citations
Cites
pH-Dependent partitioning in room temperature ionic liquids
Visser, A. E., Swatloski, R. P., & Rogers, R. D. (2000) · Green Chemistry · doi:10.1039/a908888a · Cited by 281
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Gebbie, M. A., Smith, A. M., Dobbs, H. A., Lee, A. A., Warr, G. G., Banquy, X., Valtiner, M., Rutland, M. W., Israelachvili, J. N., Perkin, S., et al. (2017) · Chemical Communications · doi:10.1039/c6cc08820a · Cited by 382
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Liu, H., Liu, Y., & Li, J. (2010) · Physical Chemistry Chemical Physics · doi:10.1039/b921469k · Cited by 372
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Wang, Y., Jiang, W., Yan, T., & Voth, G. A. (2007) · Accounts of Chemical Research · doi:10.1021/ar700160p · Cited by 331
Araque, J. C., Hettige, J. J., & Margulis, C. J. (2015) · The Journal of Physical Chemistry B · doi:10.1021/acs.jpcb.5b05506 · Cited by 320
Tsuzuki, S., Shinoda, W., Saito, H., Mikami, M., Tokuda, H., & Watanabe, M. (2009) · The Journal of Physical Chemistry B · doi:10.1021/jp811128b · Cited by 262
Turton, D. A., Hunger, J., Stoppa, A., Hefter, G., Thoman, A., Walther, M., Buchner, R., & Wynne, K. (2009) · Journal of the American Chemical Society · doi:10.1021/ja903315v · Cited by 261
Yochelis, A. (2014) · Physical Chemistry Chemical Physics · doi:10.1039/c3cp55002h · Cited by 33
Metadata
- Authors
- Triolo, A., Russina, O., Bleif, H.-J., & Di Cola, E.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-02-28
- Volume
- 111
- Issue
- 18
- Pages
- 4641-4644
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2128228409
- Cited by
- 1,282
- References
- 1
- FWCI
- 26.98
- Type
- journal article
- Language
- en
- Open access
- closed
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