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Coherent Carbon Cryogel−Ammonia Borane Nanocomposites for H2 Storage
Abstract
Coherent carbon cryogel-ammonia borane (C-AB) nanocomposites were synthesized, and improved H2 storage properties are reported. Porous carbon cryogels were impregnated with AB in tetrahydrofuran solution at 25 degrees C under argon; 30% of the carbon cryogel pore volume was filled to produce a 24 wt % C-AB nanocomposite. Nitrogen sorption isotherms, X-ray diffraction, differential scanning calorimetry, differential thermal/thermal gravimetric analyses, mass spectrometry, and 11B NMR were used to characterize the coherent C-AB nanocomposites. Findings include a merged two-step hydrogen release reaction with an appreciable reduction in the dehydrogenation temperature to <90 degrees C as well as the suppression of borazine release. The possible nanosize effects on the H2 storage properties are discussed.
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Cites
Materials for hydrogen storage
Züttel, A. (2003) · Materials Today · doi:10.1016/s1369-7021(03)00922-2 · Cited by 2,216
Carbon-supported platinum catalysts for on-site hydrogen generation from NaBH4 solution
Bai, Y., Wu, C., Wu, F., & Yi, B. (2006) · Materials Letters · doi:10.1016/j.matlet.2005.12.119 · Cited by 223
Cited by
Nanomaterials for energy conversion and storage
Zhang, Q., Uchaker, E., Candelaria, S. L., & Cao, G. (2013) · Chemical Society Reviews · doi:10.1039/c3cs00009e · Cited by 1,532
Self-citationAdsorption of VOCs onto engineered carbon materials: A review
Zhang, X., Gao, B., Creamer, A. E., Cao, C., & Li, Y. (2017) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2017.05.013 · Cited by 1,479
Ammonia-Borane and Related Compounds as Dihydrogen Sources
Staubitz, A., Robertson, A. P. M., & Manners, I. (2010) · Chemical Reviews · doi:10.1021/cr100088b · Cited by 1,247
B–N compounds for chemical hydrogenstorage
Hamilton, C. W., Baker, R. T., Staubitz, A., & Manners, I. (2009) · Chem. Soc. Rev. · doi:10.1039/b800312m · Cited by 1,087
Nanomaterials for renewable energy production and storage
Chen, X., Li, C., Grätzel, M., Kostecki, R., & Mao, S. S. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35230c · Cited by 1,015
Metadata
- Authors
- Feaver, A., Sepehri, S., Shamberger, P., Stowe, A., Autrey, T., & Cao, G.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-06-14
- Volume
- 111
- Issue
- 26
- Pages
- 7469-7472
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2144077080
- Cited by
- 180
- References
- 2
- FWCI
- 9.51
- Type
- journal article
- Language
- en
- Open access
- closed
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- Feaver, A., Sepehri, S., Shamberger, P., Stowe, A., Autrey, T., & Cao, G. (2007). Coherent Carbon Cryogel−Ammonia Borane Nanocomposites for H2 Storage. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp072448t
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