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Hydroxyl-Induced Wetting of Metals by Water at Near-Ambient Conditions
Open accessAbstract
High Resolution Image Download MS PowerPoint Slide We report different wetting properties of Cu(110) and Cu(111) at near-ambient conditions using in situ photoemission spectroscopy. At near-ambient conditions of pressure (1 Torr) and temperature (295 K), the Cu(110) surface is covered with a mixed OH and H 2 O layer, whereas the Cu(111) surface remains clean and adsorbate-free. We show that wetting is controlled by the presence of OH groups on the surface, acting as anchors for water adsorption. Hydroxylation of the Cu(110) surface is facilitated by a lower activation barrier for water dissociation compared to Cu(111).
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Cited by
The Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis
Dau, H., Limberg, C., Reier, T., Risch, M., Roggan, S., & Strasser, P. (2010) · ChemCatChem · doi:10.1002/cctc.201000126 · Cited by 1,783
Metadata
- Authors
- Yamamoto, S., Andersson, K., Bluhm, H., Ketteler, G., Starr, D. E., Schiros, T., Ogasawara, H., Pettersson, L. G. M., Salmeron, M., & Nilsson, A.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-05-16
- Volume
- 111
- Issue
- 22
- Pages
- 7848-7850
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W1992212075
- Cited by
- 160
- References
- 0
- FWCI
- 4.63
- Type
- journal article
- Language
- en
- Open access
- bronze
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- CoChat. (2026). Citation check: Hydroxyl-Induced Wetting of Metals by Water at Near-Ambient Conditions. https://app.cochat.ai/papers/10.1021/jp0731654
- The paper
- Yamamoto, S., Andersson, K., Bluhm, H., Ketteler, G., Starr, D. E., Schiros, T., Ogasawara, H., Pettersson, L. G. M., Salmeron, M., & Nilsson, A. (2007). Hydroxyl-Induced Wetting of Metals by Water at Near-Ambient Conditions. The Journal of Physical Chemistry C. https://doi.org/10.1021/jp0731654
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