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Photoinduced Carrier Generation in P3HT/PCBM Bulk Heterojunction Materials

Hwang, In-Wook, Moses, Daniel, Heeger, Alan J.·2008·The Journal of Physical Chemistry C

Abstract

Using ultrafast spectroscopy, we have investigated the generation of mobile carriers in bulk heterojunction (BHJ) blends of regioregular poly(3-hexylthiophene), rrP3HT and the [6,6]-phenyl-C 61 butyric acid methyl ester fullerene derivative, PCBM. Mobile carriers are generated via a two-step process: initial ultrafast charge separation to an intermediate charge transfer (CT) bound state, followed by the transfer of carriers onto the bicontinuous networks. The yield of mobile carriers is decreased by recombination during the time spent in the CT bound state. After annealing the BHJ blends, the recombination loss of mobile carriers is reduced by a factor of 2.5, consistent with the observed increase in photovoltaic conversion efficiency.

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Metadata

Authors
Hwang, I.-W., Moses, D., & Heeger, A. J.
Venue
The Journal of Physical Chemistry C
Published
2008-02-23
Volume
112
Issue
11
Pages
4350-4354
ISSN
  • 1932-7447 (ISSN-L)
  • 1932-7455
OpenAlex
W1973862377
Cited by
355
References
0
FWCI
34.37
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Photoinduced Carrier Generation in P3HT/PCBM Bulk Heterojunction Materials. https://app.cochat.ai/papers/10.1021/jp075565x
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Hwang, I.-W., Moses, D., & Heeger, A. J. (2008). Photoinduced Carrier Generation in P3HT/PCBM Bulk Heterojunction Materials. The Journal of Physical Chemistry C. https://doi.org/10.1021/jp075565x

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