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Estimation of Surface Oxide on Surfactant-Free Gold Nanoparticles Laser-Ablated in Water
Abstract
Surfactant-free gold nanoparticles were prepared by laser ablation of a gold metal plate in water. The nanoparticles were characterized by absorption spectroscopy, ζ-potential measurements, and XPS spectroscopy. The nanoparticles are negatively charged because the surface atoms are partially oxidized to Au−O -, according to the literature by Sacher and co-workers ( J. Phys. Chem. B, 2004, 108, 16864). We further examined electrostatic interactions between nanoparticle and cationic surfactants. It was found that the surfactant cations attach to the particle surface, neutralizing the particle charge. Taking advantage of the electrostatic interactions, we estimated that 3.3−6.6% of the surface gold atoms was oxidized in water.
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Cites
Formation of Stable Platinum Nanoparticles by Laser Ablation in Water
Mafuné, F., Kohno, J.-Y., Takeda, Y., & Kondow, T. (2003) · The Journal of Physical Chemistry B · doi:10.1021/jp021580k · Cited by 265
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Cited by
Laser Synthesis and Processing of Colloids: Fundamentals and Applications
Zhang, D., Gökce, B., & Barcikowski, S. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00468 · Cited by 1,344
Laser ablation synthesis in solution and size manipulation of noble metal nanoparticles
Amendola, V., & Meneghetti, M. (2009) · Physical Chemistry Chemical Physics · doi:10.1039/b900654k · Cited by 1,020
Amendola, V., & Meneghetti, M. (2013) · Phys. Chem. Chem. Phys. · doi:10.1039/c2cp42895d · Cited by 758
Pulsed laser ablation based synthesis of colloidal metal nanoparticles for catalytic applications
Zhang, J., Chaker, M., & Ma, D. (2017) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2016.07.050 · Cited by 264
Kanitz, A., Kalus, M.-R., Gurevich, E. L., Ostendorf, A., Barcikowski, S., & Amans, D. (2019) · Plasma Sources Science and Technology · doi:10.1088/1361-6595/ab3dbe · Cited by 195
Metadata
- Authors
- Muto, H., Yamada, K., Miyajima, K., & Mafuné, F.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-10-26
- Volume
- 111
- Issue
- 46
- Pages
- 17221-17226
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2072516544
- Cited by
- 161
- References
- 1
- FWCI
- 4.34
- Type
- journal article
- Language
- en
- Open access
- closed
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- Muto, H., Yamada, K., Miyajima, K., & Mafuné, F. (2007). Estimation of Surface Oxide on Surfactant-Free Gold Nanoparticles Laser-Ablated in Water. The Journal of Physical Chemistry C. https://doi.org/10.1021/jp075582m
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