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Physical Properties of Ionic Liquids Consisting of the 1-Butyl-3-Methylimidazolium Cation with Various Anions and the Bis(trifluoromethylsulfonyl)imide Anion with Various Cations
Abstract
Physical properties of 4 room-temperature ionic liquids consisting of the 1-butyl-3-methylimidazolium cation with various perfluorinated anions and the bis(trifluoromethylsulfonyl)imide (Tf2N-) anion with 12 pyrrolidinium-, ammonium-, and hydroxyl-containing cations are reported. Electronic structure methods are used to calculate properties related to the size, shape, and dipole moment of individual ions. Experimental measurements of phase-transition temperatures, densities, refractive indices, surface tensions, solvatochromic polarities based on absorption of Nile Red, 19F chemical shifts of the Tf2N- anion, temperature-dependent viscosities, conductivities, and cation diffusion coefficients are reported. Correlations among the measured quantities as well as the use of surface tension and molar volume for estimating Hildebrand solubility parameters of ionic liquids are also discussed.
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Cites
Predicting physical properties of ionic liquids
Deetlefs, M., Seddon, K. R., & Shara, M. (2006) · Phys. Chem. Chem. Phys. · doi:10.1039/b513453f · Cited by 411
Cited by
Wojnarowska, Z., Feng, H., Fu, Y., Cheng, S., Carroll, B., Kumar, R., Novikov, V. N., Kisliuk, A. M., Saito, T., Kang, N.-G., et al. (2017) · Macromolecules · doi:10.1021/acs.macromol.7b01217 · Cited by 116
Deepika, Juneja, S., & Pandey, S. (2022) · Journal of Chemical & Engineering Data · doi:10.1021/acs.jced.2c00495 · Cited by 70
Metadata
- Authors
- Jin, H., O'Hare, B., Dong, J., Arzhantsev, S., Baker, G. A., Wishart, J. F., Benesi, A. J., & Maroncelli, M.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-12-11
- Volume
- 112
- Issue
- 1
- Pages
- 81-92
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2036186305
- Cited by
- 422
- References
- 1
- FWCI
- 11.60
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Physical Properties of Ionic Liquids Consisting of the 1-Butyl-3-Methylimidazolium Cation with Various Anions and the Bis(trifluoromethylsulfonyl)imide Anion with Various Cations. https://app.cochat.ai/papers/10.1021/jp076462h
- The paper
- Jin, H., O'Hare, B., Dong, J., Arzhantsev, S., Baker, G. A., Wishart, J. F., Benesi, A. J., & Maroncelli, M. (2008). Physical Properties of Ionic Liquids Consisting of the 1-Butyl-3-Methylimidazolium Cation with Various Anions and the Bis(trifluoromethylsulfonyl)imide Anion with Various Cations. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp076462h
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
