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Cited by 323

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Synthesis of Mesoporous α-Fe2O3 Nanostructures for Highly Sensitive Gas Sensors and High Capacity Anode Materials in Lithium Ion Batteries

Sun, Bing, Horvat, Josip, Kim, Hyun Soo, Kim, Woo-Seong, Ahn, Jungho, Wang, Guoxiu·2010·The Journal of Physical Chemistry C

Abstract

Mesoporous α-Fe 2 O 3 materials were prepared in large quantity by the soft template synthesis method using the triblock copolymer surfactant F127 as the template. Nitrogen adsorption−desorption isothermal measurements and transmission electron microscope observation revealed that the as-prepared mesoporous α-Fe 2 O 3 nanostructures have large mesopores in a wide size range of 5−30 nm. It has been found that the Morin transition depends on thermal history of mesoporous α-Fe 2 O 3, which is driven by surface anisotropy. Superparamagnetic behavior of mesoporous α-Fe 2 O 3 is also associated with surface spins with blocking temperature around 50 K. When applied as gas sensors, mesoporous α-Fe 2 O 3 nanostructures exhibited high gas sensitivity toward acetic acid and ethanol gas. As anodes in lithium ion cells, mesoporous α-Fe 2 O 3 materials show a high specific capacity of 1360 mAh/g with excellent cycling stability and high rate capacity.

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Metadata

Authors
Sun, B., Horvat, J., Kim, H. S., Kim, W.-S., Ahn, J., & Wang, G.
Venue
The Journal of Physical Chemistry C
Published
2010-10-15
Volume
114
Issue
44
Pages
18753-18761
ISSN
  • 1932-7447 (ISSN-L)
  • 1932-7455
OpenAlex
W2023882868
Cited by
323
References
1
FWCI
11.89
Type
journal article
Language
en
Open access
closed

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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