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Study of Catalytic Activity at the CuO−CeO2 Interface for CO Oxidation

Jia, Ai-Ping, Jiang, Shi-Yu, Lu, Ji-Qing, Luo, Meng-Fei·2010·The Journal of Physical Chemistry C

Abstract

A series of CuO/CeO 2 and inverse CeO 2 /CuO catalysts were prepared by an incipient wetness impregnation method and tested for CO oxidation. Crystallite sizes of CeO 2 and CuO were evaluated by X-ray diffraction and N 2 O chemisorption, as well as transmission electron microscopy. It was found that a CuO(5)/CeO 2 -500 catalyst with a CuO crystallite size of 4.1 nm and a CeO 2 (5)/CuO-500 catalyst with a CeO 2 crystallite size of 4.0 nm had identical activities, indicating that the reaction may occur at the interface of CuO−CeO 2 . According to the turnover frequency based on CuO sites located on the CuO−CeO 2 interface, the activity on the larger CuO crystallite was much higher than that on the smaller one, indicating that CuO−CeO 2 catalyst for CO oxidation is structure-sensitive. The enhanced activity was ascribed to a higher density of chemisorbed CO on the active sites for the larger CuO crystallite.

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Metadata

Authors
Jia, A.-P., Jiang, S.-Y., Lu, J.-Q., & Luo, M.-F.
Venue
The Journal of Physical Chemistry C
Published
2010-11-15
Volume
114
Issue
49
Pages
21605-21610
ISSN
  • 1932-7447 (ISSN-L)
  • 1932-7455
OpenAlex
W2312490868
Cited by
215
References
0
FWCI
4.48
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Study of Catalytic Activity at the CuO−CeO2 Interface for CO Oxidation. https://app.cochat.ai/papers/10.1021/jp108556u
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Jia, A.-P., Jiang, S.-Y., Lu, J.-Q., & Luo, M.-F. (2010). Study of Catalytic Activity at the CuO−CeO2 Interface for CO Oxidation. The Journal of Physical Chemistry C. https://doi.org/10.1021/jp108556u

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