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Study of Catalytic Activity at the CuO−CeO2 Interface for CO Oxidation
Abstract
A series of CuO/CeO 2 and inverse CeO 2 /CuO catalysts were prepared by an incipient wetness impregnation method and tested for CO oxidation. Crystallite sizes of CeO 2 and CuO were evaluated by X-ray diffraction and N 2 O chemisorption, as well as transmission electron microscopy. It was found that a CuO(5)/CeO 2 -500 catalyst with a CuO crystallite size of 4.1 nm and a CeO 2 (5)/CuO-500 catalyst with a CeO 2 crystallite size of 4.0 nm had identical activities, indicating that the reaction may occur at the interface of CuO−CeO 2 . According to the turnover frequency based on CuO sites located on the CuO−CeO 2 interface, the activity on the larger CuO crystallite was much higher than that on the smaller one, indicating that CuO−CeO 2 catalyst for CO oxidation is structure-sensitive. The enhanced activity was ascribed to a higher density of chemisorbed CO on the active sites for the larger CuO crystallite.
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Cited by
On the Synergetic Catalytic Effect in Heterogeneous Nanocomposite Catalysts
Shi, J. (2013) · Chemical Reviews · doi:10.1021/cr3002752 · Cited by 652
Wang, W.-W., Yu, W.-Z., Du, P.-P., Xu, H., Jin, Z., Si, R., Ma, C., Shi, S., Jia, C.-J., & Yan, C.-H. (2017) · ACS Catalysis · doi:10.1021/acscatal.6b03234 · Cited by 444
Metadata
- Authors
- Jia, A.-P., Jiang, S.-Y., Lu, J.-Q., & Luo, M.-F.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-11-15
- Volume
- 114
- Issue
- 49
- Pages
- 21605-21610
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2312490868
- Cited by
- 215
- References
- 0
- FWCI
- 4.48
- Type
- journal article
- Language
- en
- Open access
- closed
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- Jia, A.-P., Jiang, S.-Y., Lu, J.-Q., & Luo, M.-F. (2010). Study of Catalytic Activity at the CuO−CeO2 Interface for CO Oxidation. The Journal of Physical Chemistry C. https://doi.org/10.1021/jp108556u
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