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The Behavior of Flexible MIL-53(Al) upon CH4and CO2Adsorption
Open accessAbstract
The use of the osmotic thermodynamic model, combined with a series of methane and carbon dioxide gas adsorption experiments at various temperatures, has allowed shedding some new light on the fascinating phase behavior of flexible MIL-53(Al) metal−organic frameworks. A generic temperature-loading phase diagram has been derived; it is shown that the breathing effect in MIL-53 is a very general phenomenon, which should be observed in a limited temperature range regardless of the guest molecule. In addition, the previously proposed stress model for the structural transitions of MIL-53 is shown to be transferable from xenon to methane adsorption. The stress model also provides a theoretical framework for understanding the existence of lp / np phase mixtures at pressures close to the breathing transition pressure, without having to invoke an inhomogeneous distribution of the adsorbate in the porous sample.
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Cited by
CO2 Capture and Separations Using MOFs: Computational and Experimental Studies
Yu, J., Xie, L.-H., Li, J.-R., Ma, Y., Seminario, J. M., & Balbuena, P. B. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00626 · Cited by 1,047
Galizia, M., Chi, W. S., Smith, Z. P., Merkel, T. C., Baker, R. W., & Freeman, B. D. (2017) · Macromolecules · doi:10.1021/acs.macromol.7b01718 · Cited by 989
Metal–Organic Frameworks for Water Harvesting from Air
Kalmutzki, M. J., Diercks, C. S., & Yaghi, O. M. (2018) · Advanced Materials · doi:10.1002/adma.201704304 · Cited by 772
Characterization of the adsorption site energies and heterogeneous surfaces of porous materials
Kumar, K. V., Gadipelli, S., Wood, B., Ramisetty, K. A., Stewart, A. A., Howard, C. A., Brett, D. J. L., & Rodriguez-Reinoso, F. (2019) · Journal of Materials Chemistry A · doi:10.1039/c9ta00287a · Cited by 384
Mixed matrix membranes based on amine and non-amine MIL-53(Al) in Pebax® MH-1657 for CO 2 separation
Meshkat, S., Kaliaguine, S., & Rodrigue, D. (2018) · Separation and Purification Technology · doi:10.1016/j.seppur.2018.02.038 · Cited by 265
Metadata
- Authors
- Boutin, A., Coudert, F.-X., Springuel-Huet, M.-A., Neimark, A. V., Férey, G., & Fuchs, A. H.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-12-01
- Volume
- 114
- Issue
- 50
- Pages
- 22237-22244
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2157013974
- Cited by
- 237
- References
- 0
- FWCI
- 6.60
- Type
- journal article
- Language
- en
- Open access
- green
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- Boutin, A., Coudert, F.-X., Springuel-Huet, M.-A., Neimark, A. V., Férey, G., & Fuchs, A. H. (2010). The Behavior of Flexible MIL-53(Al) upon CH4and CO2Adsorption. The Journal of Physical Chemistry C. https://doi.org/10.1021/jp108710h
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