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Cited by 190

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Controllable ZnO Architectures by Ethanolamine-Assisted Hydrothermal Reaction for Enhanced Photocatalytic Activity

Wang, Xinjuan, Zhang, Qinglin, Wan, Qiang, Dai, Guozhang, Zhou, Chunjiao, Zou, Bingsuo·2011·The Journal of Physical Chemistry C

Abstract

Controllable ZnO architectures with different morphologies were synthesized via an ethanolamine-assisted one-pot hydrothermal method. By adjusting reaction conditions such as the molar ratio between Zn(OAc) 2 and NaOH and the volume ratio of the ethanolamine/water, the flowerlike, spindlelike, swordlike, and umbellarlike ZnO architectures of the hexagonal phase have been obtained. The as-prepared ZnO products were characterized by FE-SEM, TEM, XRD, BET, PL, and Raman spectroscopy. The ethanolamine significantly influenced the morphology of ZnO products, which is related to the competitive adsorption between ethanolamine and [Zn(OH) 4 ] 2− to ZnO nuclei. Their PL spectra depend on their morphologies and phase structures. The morphology-dependent photocatalytic performances in the degradation of methylene blue under UV illumination were observed, in which the flowerlike ZnO structures exhibit highest activity for their most irregular surface Zn sites.

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Metadata

Authors
Wang, X., Zhang, Q., Wan, Q., Dai, G., Zhou, C., & Zou, B.
Venue
The Journal of Physical Chemistry C
Published
2011-01-21
Volume
115
Issue
6
Pages
2769-2775
ISSN
  • 1932-7447 (ISSN-L)
  • 1932-7455
OpenAlex
W2328062150
Cited by
190
References
2
FWCI
11.46
Type
journal article
Language
en
Open access
closed

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