The DOI matches its Crossref record; 27 of the 27 references it cites were found in a registry or an index.
Formation of Fluorescent Metal (Au, Ag) Nanoclusters Capped in Bovine Serum Albumin Followed by Fluorescence and Spectroscopy
Abstract
Fluorescent noble metal (Au, Ag) nanoclusters have been biolabeled to bovine serum albumin (BSA) by wet chemistry. Spectroscopic and fluorescence investigations relate the role of the pH and the nature of the reducing agent to the size and the oxidation state of metal clusters. Blue-emitting (λ = 450 nm) small gold nanoclusters (eight atoms) prepared at pH 8 weakly bonded to BSA grow at higher pH to form red-emitting (λ = 690 nm) bigger clusters (25 atoms) covalently bonded to BSA via the sulfur group. X-ray photoelectron spectroscopy (XPS) measurements indicate the presence of Au(I) only for the big clusters. Small silver nanoclusters labeled to the protein with a fluorescence emission in the red region are synthesized in the presence of a strong reducing agent and present only Ag(0). Steady-state and lifetime measurements confirm the crucial impact of the size and the oxidation state of Au(I) on the stabilization of the metal core inside the protein and on the presence of a long lifetime component (τ > 170 ns).
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Cites
Infrared spectroscopy of proteins
Barth, A. (2007) · Biochimica et Biophysica Acta (BBA) - Bioenergetics · doi:10.1016/j.bbabio.2007.06.004 · Cited by 5,129
Protein-Directed Synthesis of Highly Fluorescent Gold Nanoclusters
Xie, J., Zheng, Y., & Ying, J. Y. (2009) · Journal of the American Chemical Society · doi:10.1021/ja806804u · Cited by 2,590
Correlating the Crystal Structure of A Thiol-Protected Au25 Cluster and Optical Properties
Zhu, M., Aikens, C. M., Hollander, F. J., Schatz, G. C., & Jin, R. (2008) · Journal of the American Chemical Society · doi:10.1021/ja801173r · Cited by 2,348
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On the Ligand’s Role in the Fluorescence of Gold Nanoclusters
Wu, Z., & Jin, R. M. (2010) · Nano Letters · doi:10.1021/nl101225f · Cited by 1,372
Highly Fluorescent Noble-Metal Quantum Dots
Zheng, J., Nicovich, P. R., & Dickson, R. M. (2006) · Annual Review of Physical Chemistry · doi:10.1146/annurev.physchem.58.032806.104546 · Cited by 1,287
Oligonucleotide-Stabilized Ag Nanocluster Fluorophores
Richards, C. I., Choi, S., Hsiang, J.-C., Antoku, Y., Vosch, T., Bongiorno, A., Tzeng, Y.-L., & Dickson, R. M. (2008) · Journal of the American Chemical Society · doi:10.1021/ja8005644 · Cited by 861
Lin, C.-A. J., Yang, T.-Y., Lee, C.-H., Huang, S. H., Sperling, R. A., Zanella, M., Li, J. K., Shen, J.-L., Wang, H.-H., Yeh, H.-I., et al. (2009) · ACS Nano · doi:10.1021/nn800632j · Cited by 731
High Quantum Yield Blue Emission from Water-Soluble Au8 Nanodots
Zheng, J., Petty, J. T., & Dickson, R. M. (2003) · Journal of the American Chemical Society · doi:10.1021/ja035473v · Cited by 725
Individual Water-Soluble Dendrimer-Encapsulated Silver Nanodot Fluorescence
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Engineering ultrasmall water-soluble gold and silver nanoclusters for biomedical applications
Luo, Z., Zheng, K., & Xie, J. (2014) · Chem. Commun. · doi:10.1039/c3cc47512c · Cited by 441
Luminescent Noble Metal Nanoclusters as an Emerging Optical Probe for Sensor Development
Yuan, X., Luo, Z., Yu, Y., Yao, Q., & Xie, J. (2013) · Chemistry – An Asian Journal · doi:10.1002/asia.201201236 · Cited by 328
Use of Fluorescent DNA-Templated Gold/Silver Nanoclusters for the Detection of Sulfide Ions
Chen, W.-Y., Lan, G.-Y., & Chang, H.-T. (2011) · Analytical Chemistry · doi:10.1021/ac202162u · Cited by 283
Huang, J., Xiang, Y., Li, J., Kong, Q., Zhai, H., Xu, R., Yang, F., Sun, X., & Guo, Y. (2021) · Biosensors and Bioelectronics · doi:10.1016/j.bios.2021.113601 · Cited by 84
Metadata
- Authors
- Le Guével, X., Hötzer, B., Jung, G., Hollemeyer, K., Trouillet, V., & Schneider, M.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-05-13
- Volume
- 115
- Issue
- 22
- Pages
- 10955-10963
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2333610383
- Cited by
- 384
- References
- 27
- FWCI
- 14.25
- Type
- journal article
- Language
- en
- Open access
- closed
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