The DOI matches its Crossref record; 13 of the 13 references it cites were found in a registry or an index.
Flexible Electrically Conductive Nanocomposite Membrane Based on Bacterial Cellulose and Polyaniline
Abstract
The novel conductive polyaniline/bacterial cellulose (PANI/BC) nanocomposite membranes have been synthesized in situ by oxidative polymerization of aniline with ammonium persulfate as an oxidant and BC as a template. The resulting PANI-coated BC nanofibrils formed a uniform and flexible membrane. It was found that the PANI nanoparticles deposited on the surface of BC connected to form a continuous nanosheath by taking along the BC template, which greatly increases the thermal stability of BC. The content of PANI and the electrical conductivity of composites increased with increasing reaction time from 30 to 90 min, while the conductivity decreased because of the aggregation of PANI particles by further prolonging the reaction time. In addition, the acids remarkably improve the accessibility and reactivity of the hydroxyl groups of BC. The results indicate that the composites exhibit excellent electrical conductivity (the highest value was 5.0 × 10(-2) S/cm) and good mechanical properties (Young's modulus was 5.6 GPa and tensile strength was 95.7 MPa). Moreover, the electrical conductivity of the membrane is sensitive to the strain. This work provides a straightforward method to prepare flexible films with high conductivity and good mechanical properties, which could be applied in sensors, flexible electrodes, and flexible displays. It also opens a new field of potential applications of BC materials.
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Cites
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Toward Flexible Polymer and Paper‐Based Energy Storage Devices
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A Nanocellulose Polypyrrole Composite Based on Microfibrillated Cellulose from Wood
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Cited by
Biodegradable and electrically conducting polymers for biomedical applications
Guo, B., Glavas, L., & Albertsson, A.-C. (2013) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2013.06.003 · Cited by 592
Biosynthesis, production and applications of bacterial cellulose
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Lai, F., Miao, Y.-E., Zuo, L., Lu, H., Huang, Y., & Liu, T. (2016) · Small · doi:10.1002/smll.201600412 · Cited by 451
Functionalized bacterial cellulose derivatives and nanocomposites
Hu, W., Chen, S., Yang, J., Li, Z., & Wang, H. (2014) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2013.09.102 · Cited by 448
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Metadata
- Authors
- Hu, W., Chen, S., Yang, Z., Liu, L., & Wang, H.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-06-14
- Volume
- 115
- Issue
- 26
- Pages
- 8453-8457
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W1965614340
- Cited by
- 321
- References
- 13
- FWCI
- 7.16
- Type
- journal article
- Language
- en
- Open access
- closed
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- Hu, W., Chen, S., Yang, Z., Liu, L., & Wang, H. (2011). Flexible Electrically Conductive Nanocomposite Membrane Based on Bacterial Cellulose and Polyaniline. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp204422v
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