The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Characterization of Oxygen Vacancy Associates within Hydrogenated TiO2: A Positron Annihilation Study
Abstract
This paper introduces a novel method for characterizing the oxygen vacancy associates in hydrogenation-modified TiO 2 by using a positron annihilation lifetime spectroscopy (PALS). It was found that a huge number of small neutral Ti 3+ –oxygen vacancy associates, some larger size vacancy clusters, and a few voids of vacancy associates were introduced into hydrogenated TiO 2 . The defects blurred the atomic lattice high-resolution transmission electron microscopy (HRTEM) images and brought about the emergence of new Raman vibration. X-ray photoelectron spectroscopy (XPS) measurement indicated that the concentration of oxygen vacancies was 3% in the TiO 2 lattice. The photoluminescence (PL) spectroscopy, photocurrent, and degradation of methylene blue indicated that the oxygen vacancy associates introduced by hydrogenation retarded the charge recombination and therefore improved the photocatalytic activity remarkably.
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Cites
Electrochemical Photolysis of Water at a Semiconductor Electrode
FUJISHIMA, A., & HONDA, K. (1972) · Nature · doi:10.1038/238037a0 · Cited by 34,169
Cited by
Wang, Z., Yang, C., Lin, T., Yin, H., Chen, P., Wan, D., Xu, F., Huang, F., Lin, J., Xie, X., et al. (2013) · Advanced Functional Materials · doi:10.1002/adfm.201300486 · Cited by 719
Kapilashrami, M., Zhang, Y., Liu, Y.-S., Hagfeldt, A., & Guo, J. (2014) · Chemical Reviews · doi:10.1021/cr5000893 · Cited by 508
Self-citationLi, B., Zhao, Z., Zhou, Q., Meng, B., Meng, X., & Qiu, J. (2014) · Chemistry – A European Journal · doi:10.1002/chem.201402664 · Cited by 95
Metadata
- Authors
- Jiang, X., Zhang, Y., Jiang, J., Rong, Y., Wang, Y., Wu, Y., & Pan, C.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-10-11
- Volume
- 116
- Issue
- 42
- Pages
- 22619-22624
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2327857279
- Cited by
- 585
- References
- 1
- FWCI
- 41.32
- Type
- journal article
- Language
- en
- Open access
- closed
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