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Cited by 433

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MoS2/CdS Heterojunction with High Photoelectrochemical Activity for H2 Evolution under Visible Light: The Role of MoS2

Liu, Ying, Yu, Yu-Xiang, Zhang, Wei-De·2013·The Journal of Physical Chemistry C

Abstract

MoS 2 /CdS p-n heterojunction films with high photoelectrochemical activity for H 2 evolution under visible light were successfully prepared by electrodeposition followed by chemical bath deposition. The films were characterized by X-ray diffraction, scanning electron microscopy, UV–visible absorption, X-ray photoemission spectroscopy, photoluminescence, and photoelectrochemical response. The MoS 2 /CdS heterostructure shows much higher visible-light photoelectrocatalytic activity and higher stability toward the water splitting than pure CdS film. The MoS 2 /CdS film with an optimal ratio of 0.14% exhibits the highest photocurrent of 28 mA/cm 2 and the highest IPCE of ca. 28% at 420 nm at 0 V vs Ag/AgCl. The critical role of MoS 2 in the MoS 2 /CdS film was investigated. The improved photoelectrochemical performance of the MoS 2 /CdS heterojunction film was attributed to the visible light absorption enhanced by MoS 2 and the formation of a p-n junction between CdS and MoS 2, which accelerates the effective separation of photogenerated carriers by the internal electrostatic field in the junction region.

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Crossref · 10.1021/jp4009652

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Metadata

Authors
Liu, Y., Yu, Y.-X., & Zhang, W.-D.
Venue
The Journal of Physical Chemistry C
Published
2013-06-18
Volume
117
Issue
25
Pages
12949-12957
ISSN
  • 1932-7447 (ISSN-L)
  • 1932-7455
OpenAlex
W2327037001
Cited by
433
References
2
FWCI
14.67
Type
journal article
Language
en
Open access
closed

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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