The DOI matches its Crossref record; 15 of the 15 references it cites were found in a registry or an index.
Unifying Kinetic and Thermodynamic Analysis of 2 e– and 4 e– Reduction of Oxygen on Metal Surfaces
Open accessAbstract
Abstract Oxygen electrochemistry has played a key role in developing the foundational understanding of surface electrocatalysis. In this work, we develop a detailed microkinetic model for the oxygen reduction reaction based on density functional theory calculations and molucular dynamics simulations. The developed microkinetic model has a reaction order of 1 in O2 and a 59 mV/dec Tafel slope in the potential range where the Pt(111) surface is dominated by OH adsorption. Using calculated scaling and Brønsted–Evans–Polanyi relations, we extend this analysis to calculate the activity on materials with a varying OH binding energy. We demonstrate the existence of a kinetic activity volcano which is in close agreement with the thermodynamic activity volcano derived earlier. Both of these analyses identify an activity optimum around 0.1 eV weaker binding of OH relative to Pt(111). The predictions of the kinetic activity volcano are in close agreement with several RDE experiments on metals and Pt alloys. On the basis of rate control analysis and Sabatier analysis, we demonstrate the close connection between the kinetic and thermodynamic formulations for oxygen reduction. We further examine trends in 2e– reduction of O2 to H2O2 and show a similar correspondence between the thermodynamic and kinetic activity volcano with the activity optimum around 0.3 eV weaker OH binding than Pt(111). On the basis of rate control analysis, we show that many elementary steps play a key role in determining the selectivity. This emphasizes the importance of detailed kinetic analysis for addressing trends in selectivity.
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Cites
CRC Handbook of Chemistry and Physics
(2014) · doi:10.1201/b17118 · Cited by 57,706
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode
Nørskov, J. K., Rossmeisl, J., Logadottir, A., Lindqvist, L., Kitchin, J. R., Bligaard, T., & Jónsson, H. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp047349j · Cited by 13,153
Self-citationUniversality in Oxygen Evolution Electrocatalysis on Oxide Surfaces
Man, I. C., Su, H., Calle‐Vallejo, F., Hansen, H. A., Martínez, J. I., Inoglu, N. G., Kitchin, J., Jaramillo, T. F., Nørskov, J. K., & Rossmeisl, J. (2011) · ChemCatChem · doi:10.1002/cctc.201000397 · Cited by 4,769
Self-citationImproved Oxygen Reduction Activity on Pt 3 Ni(111) via Increased Surface Site Availability
Stamenkovic, V. R., Fowler, B., Mun, B. S., Wang, G., Ross, P. N., Lucas, C. A., & Marković, N. M. (2007) · Science · doi:10.1126/science.1135941 · Cited by 4,421
Computational high-throughput screening of electrocatalytic materials for hydrogen evolution
Greeley, J., Jaramillo, T. F., Bonde, J., Chorkendorff, I., & Nørskov, J. K. (2006) · Nature Materials · doi:10.1038/nmat1752 · Cited by 4,097
Self-citationAlloys of platinum and early transition metals as oxygen reduction electrocatalysts
Greeley, J., Stephens, I. E. L., Bondarenko, A. S., Johansson, T. P., Hansen, H. A., Jaramillo, T. F., Rossmeisl, J., Chorkendorff, I., & Nørskov, J. K. (2009) · Nature Chemistry · doi:10.1038/nchem.367 · Cited by 3,203
Self-citationAbild-Pedersen, F., Greeley, J., Studt, F., Rossmeisl, J., Munter, T. R., Moses, P. G., Skúlason, E., Bligaard, T., & Nørskov, J. K. (2007) · Physical Review Letters · doi:10.1103/physrevlett.99.016105 · Cited by 1,678
Self-citationZhang, J., Vukmirovic, M. B., Xu, Y., Mavrikakis, M., & Adzic, R. R. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200462335 · Cited by 1,106
Shao, M., Peles, A., & Shoemaker, K. (2011) · Nano Letters · doi:10.1021/nl2017459 · Cited by 878
Markovic, N. M., Gasteiger, H. A., & Ross, P. N. (1995) · The Journal of Physical Chemistry · doi:10.1021/j100011a001 · Cited by 736
Adsorption and Dissociation of O 2 on Pt−Co and Pt−Fe Alloys
Xu, Y., Ruban, A. V., & Mavrikakis, M. (2004) · Journal of the American Chemical Society · doi:10.1021/ja031701+ · Cited by 636
Markovic, N., Gasteiger, H., & Ross, P. N. (1997) · Journal of The Electrochemical Society · doi:10.1149/1.1837646 · Cited by 564
Tuning the Activity of Pt(111) for Oxygen Electroreduction by Subsurface Alloying
Stephens, I. E. L., Bondarenko, A. S., Perez-Alonso, F. J., Calle-Vallejo, F., Bech, L., Johansson, T. P., Jepsen, A. K., Frydendal, R., Knudsen, B. P., Rossmeisl, J., et al. (2011) · Journal of the American Chemical Society · doi:10.1021/ja111690g · Cited by 526
Improved oxygen reduction reactivity of platinum monolayers on transition metal surfaces
Nilekar, A. U., & Mavrikakis, M. (2008) · Surface Science · doi:10.1016/j.susc.2008.05.036 · Cited by 226
Mechanism for Oxygen Reduction Reaction on Pt3Ni Alloy Fuel Cell Cathode
Sha, Y., Yu, T. H., Merinov, B. V., Shirvanian, P., & Goddard, W. A. (2012) · The Journal of Physical Chemistry C · doi:10.1021/jp303966u · Cited by 65
Cited by
Combining theory and experiment in electrocatalysis: Insights into materials design
Seh, Z. W., Kibsgaard, J., Dickens, C. F., Chorkendorff, I., Nørskov, J. K., & Jaramillo, T. F. (2017) · Science · doi:10.1126/science.aad4998 · Cited by 12,114
Self-citationUnderstanding Catalytic Activity Trends in the Oxygen Reduction Reaction
Kulkarni, A., Siahrostami, S., Patel, A., & Nørskov, J. K. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00488 · Cited by 2,742
Self-citationRecent advancements in Pt and Pt-free catalysts for oxygen reduction reaction
Nie, Y., Li, L., & Wei, Z. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00484a · Cited by 2,156
Tuning the activity of Pt alloy electrocatalysts by means of the lanthanide contraction
Escudero-Escribano, M., Malacrida, P., Hansen, M. H., Vej-Hansen, U. G., Velázquez-Palenzuela, A., Tripkovic, V., Schiøtz, J., Rossmeisl, J., Stephens, I. E. L., & Chorkendorff, I. (2016) · Science · doi:10.1126/science.aad8892 · Cited by 1,057
Electric Field Effects in Electrochemical CO 2 Reduction
Chen, L. D., Urushihara, M., Chan, K., & Nørskov, J. K. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02299 · Cited by 702
Self-citation
Metadata
- Authors
- Hansen, H. A., Viswanathan, V., & Nørskov, J. K.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-03-19
- Volume
- 118
- Issue
- 13
- Pages
- 6706-6718
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W1975598154
- Cited by
- 465
- References
- 15
- FWCI
- 7.20
- Type
- journal article
- Language
- en
- Open access
- hybrid
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