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Operando X-ray Absorption Study of the Redox Processes Involved upon Cycling of the Li-Rich Layered Oxide Li1.20Mn0.54Co0.13Ni0.13O2 in Li Ion Batteries
Abstract
Operando X-ray absorption spectroscopy investigations have been carried out to follow changes in the atomic and electronic local structures of all three transition metals for the Li 1.20 Mn 0.54 Co 0.13 Ni 0.13 O 2 layered oxide during the first and second charges and discharges of lithium batteries. The experiments were performed using a Quick-XAS monochromator on the SAMBA beamline at Synchrotron SOLEIL to record the three K-edges by edge-jumping between two energy ranges ([Mn, Co] and [Co, Ni]) every 3 min during the cycling of the battery. The results obtained especially at the Mn K-edge fully support the participation of oxygen in the reversible charge–discharge reaction of this Li- and Mn-rich layered material as a redox center and not only with oxygen loss, as was proposed previously.
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Cited by
Nickel‐Rich and Lithium‐Rich Layered Oxide Cathodes: Progress and Perspectives
Manthiram, A., Knight, J. C., Myung, S., Oh, S., & Sun, Y. (2016) · Advanced Energy Materials · doi:10.1002/aenm.201501010 · Cited by 1,202
Visualization of O-O peroxo-like dimers in high-capacity layered oxides for Li-ion batteries
McCalla, E., Abakumov, A. M., Saubanère, M., Foix, D., Berg, E. J., Rousse, G., Doublet, M.-L., Gonbeau, D., Novák, P., Van Tendeloo, G., et al. (2015) · Science · doi:10.1126/science.aac8260 · Cited by 854
Electrode–electrolyte interfaces in lithium-based batteries
Yu, X., & Manthiram, A. (2018) · Energy & Environmental Science · doi:10.1039/c7ee02555f · Cited by 649
Zuo, W., Luo, M., Liu, X., Wu, J., Liu, H., Li, J., Winter, M., Fu, R., Yang, W., & Yang, Y. (2020) · Energy & Environmental Science · doi:10.1039/d0ee01694b · Cited by 429
Electron paramagnetic resonance imaging for real-time monitoring of Li-ion batteries
Sathiya, M., Leriche, J.-B., Salager, E., Gourier, D., Tarascon, J.-M., & Vezin, H. (2015) · Nature Communications · doi:10.1038/ncomms7276 · Cited by 312
Metadata
- Authors
- Koga, H., Croguennec, L., Ménétrier, M., Mannessiez, P., Weill, F., Delmas, C., & Belin, S.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-03-10
- Volume
- 118
- Issue
- 11
- Pages
- 5700-5709
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2331624046
- Cited by
- 246
- References
- 0
- FWCI
- 11.32
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Operando X-ray Absorption Study of the Redox Processes Involved upon Cycling of the Li-Rich Layered Oxide Li1.20Mn0.54Co0.13Ni0.13O2 in Li Ion Batteries. https://app.cochat.ai/papers/10.1021/jp412197z
- The paper
- Koga, H., Croguennec, L., Ménétrier, M., Mannessiez, P., Weill, F., Delmas, C., & Belin, S. (2014). Operando X-ray Absorption Study of the Redox Processes Involved upon Cycling of the Li-Rich Layered Oxide Li1.20Mn0.54Co0.13Ni0.13O2 in Li Ion Batteries. The Journal of Physical Chemistry C. https://doi.org/10.1021/jp412197z
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