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Hybrid Lead Halide Iodide and Lead Halide Bromide in Efficient Hole Conductor Free Perovskite Solar Cell
Abstract
In this work we used CH 3 NH 3 PbI n Br 3– n (where 0 ≤ n ≤ 3) as hole conductor and light harvester in the solar cell. Various concentrations of methylammonium iodide and methylammonium bromide were studied which reveal that any composition of the hybrid CH 3 NH 3 PbI n Br 3– n can conduct holes. The hybrid perovskite was deposited in two steps, separating it to two precursors to allow better control of the perovskite composition and efficient tuning of its band gap. The X-ray diffraction reveals the change in the lattice parameter due to the introducing of the Br – ions. The hybrid iodide/bromide perovskite hole conductor free solar cells show very good stability, their power conversion efficiency achieved 8.54% under 1 sun illumination with current density of 16.2 mA/cm 2 . The results of this work open the possibility for graded structure of perovskite solar cells without the need for hole conductor.
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Stranks, S. D., Eperon, G. E., Grancini, G., Menelaou, C., Alcocer, M. J. P., Leijtens, T., Herz, L. M., Petrozza, A., & Snaith, H. J. (2013) · Science · doi:10.1126/science.1243982 · Cited by 10,413
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A Review of Perovskites Solar Cell Stability
Wang, R., Mujahid, M., Duan, Y., Wang, Z., Xue, J., & Yang, Y. (2019) · Advanced Functional Materials · doi:10.1002/adfm.201808843 · Cited by 1,310
Under the spotlight: The organic–inorganic hybrid halide perovskite for optoelectronic applications
Chen, Q., De Marco, N., Yang, Y. (., Song, T.-B., Chen, C.-C., Zhao, H., Hong, Z., Zhou, H., & Yang, Y. (2015) · Nano Today · doi:10.1016/j.nantod.2015.04.009 · Cited by 1,154
Progress on Perovskite Materials and Solar Cells with Mixed Cations and Halide Anions
Ono, L. K., Juarez-Perez, E. J., & Qi, Y. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b06001 · Cited by 593
The optoelectronic role of chlorine in CH3NH3PbI3(Cl)-based perovskite solar cells
Chen, Q., Zhou, H., Fang, Y., Stieg, A. Z., Song, T.-B., Wang, H.-H., Xu, X., Liu, Y., Lu, S., You, J., et al. (2015) · Nature Communications · doi:10.1038/ncomms8269 · Cited by 485
Recent Progress on the Long‐Term Stability of Perovskite Solar Cells
Fu, Q., Tang, X., Huang, B., Hu, T., Tan, L., Chen, L., & Chen, Y. (2018) · Advanced Science · doi:10.1002/advs.201700387 · Cited by 454
Kim, J. H., Williams, S. T., Cho, N., Chueh, C., & Jen, A. K. ‐. (2015) · Advanced Energy Materials · doi:10.1002/aenm.201401229 · Cited by 366
Can Trihalide Lead Perovskites Support Continuous Wave Lasing?
Cadelano, M., Sarritzu, V., Sestu, N., Marongiu, D., Chen, F., Piras, R., Corpino, R., Carbonaro, C. M., Quochi, F., Saba, M., et al. (2015) · Advanced Optical Materials · doi:10.1002/adom.201500229 · Cited by 82
Metadata
- Authors
- Aharon, S., Cohen, B. E., & Etgar, L.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-05-01
- Volume
- 118
- Issue
- 30
- Pages
- 17160-17165
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2332980192
- Cited by
- 227
- References
- 1
- FWCI
- 22.29
- Type
- journal article
- Language
- en
- Open access
- closed
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