The DOI matches its Crossref record; 30 of the 30 references it cites were found in a registry or an index.
Surface and Stability Characterization of a Nanoporous ZIF-8 Thin Film
Abstract
Zeolitic imidazolate frameworks (ZIFs) have been widely investigated for numerous applications including energy storage, heterogeneous catalysis, and greenhouse gas adsorption. Much of the early work has focused on the bulk properties of microcrystalline ZIFs. Herein, we focus on identifying the nature of the surface of ZIF-8 by studying a supported ZIF-8 nanoparticle film using surface characterization techniques. We have experimentally identified the presence of a zinc-rich surface terminated by carbonates and water/hydroxyl groups (in addition to the expected methylimidazole terminations) using X-ray photoelectron spectroscopy (XPS). The thermal stability of ZIF-8 thin films was also investigated using scanning electron microscopy (SEM) and temperature-programmed reaction spectroscopy (TPRS). We determined the onset of decomposition of ZIF-8 thin films to be approximately 630 K using TPRS in an ultrahigh vacuum (UHV) environment. This work presents the first characterization steps needed to study the evolution of ZIF surfaces in situ using surface characterization techniques. Such techniques are capable of determining reaction products and tracking intermediates and surface evolution in gas adsorption/reaction studies of thin films.
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Cites
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Cited by
Metal–organic frameworks for membrane-based separations
Denny, M. S., Moreton, J. C., Benz, L., & Cohen, S. M. (2016) · Nature Reviews Materials · doi:10.1038/natrevmats.2016.78 · Cited by 820
Self-citationLi, X., Gao, X., Ai, L., & Jiang, J. (2015) · Chemical Engineering Journal · doi:10.1016/j.cej.2015.03.127 · Cited by 382
Metadata
- Authors
- Tian, F., Cerro, A. M., Mosier, A. M., Wayment-Steele, H. K., Shine, R. S., Park, A., Webster, E. R., Johnson, L. E., Johal, M. S., & Benz, L.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-06-19
- Volume
- 118
- Issue
- 26
- Pages
- 14449-14456
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2313411230
- Cited by
- 284
- References
- 30
- FWCI
- 4.52
- Type
- journal article
- Language
- en
- Open access
- closed
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- Tian, F., Cerro, A. M., Mosier, A. M., Wayment-Steele, H. K., Shine, R. S., Park, A., Webster, E. R., Johnson, L. E., Johal, M. S., & Benz, L. (2014). Surface and Stability Characterization of a Nanoporous ZIF-8 Thin Film. The Journal of Physical Chemistry C. https://doi.org/10.1021/jp5041053
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