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Raman Studies of Monolayer Graphene: The Substrate Effect
Abstract
Graphene has attracted a lot of interest for fundamental studies as well as for potential applications. Till now, micromechanical cleavage (MC) of graphite has been used to produce high-quality graphene sheets on different substrates. Clear understanding of the substrate effect is important for the potential device fabrication of graphene. Here we report the results of the Raman studies of micromechanically cleaved monolayer graphene on standard SiO 2 (300 nm)/Si, single crystal quartz, Si, glass, polydimethylsiloxane (PDMS), and NiFe. Our data suggests that the Raman features of monolayer graphene are independent of the substrate used; in other words, the effect of substrate on the atomic/electronic structures of graphene is negligible for graphene made by MC. On the other hand, epitaxial monolayer graphene (EMG) on SiC substrate is also investigated. Significant blueshift of Raman bands is observed, which is attributed to the interaction of the graphene sheet with the substrate, resulting in the change of lattice constant and also the electronic structure.
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Cites
Electric Field Effect in Atomically Thin Carbon Films
Novoselov, K. S., Geim, A. K., Morozov, S. V., Jiang, D., Zhang, Y., Dubonos, S. V., Grigorieva, I. V., & Firsov, A. A. (2004) · Science · doi:10.1126/science.1102896 · Cited by 66,834
Two-dimensional gas of massless Dirac fermions in graphene
Novoselov, K. S., Geim, A. K., Morozov, S. V., Jiang, D., Katsnelson, M. I., Grigorieva, I. V., Dubonos, S. V., & Firsov, A. A. (2005) · Nature · doi:10.1038/nature04233 · Cited by 21,611
Experimental observation of the quantum Hall effect and Berry's phase in graphene
Zhang, Y., Tan, Y.-W., Stormer, H. L., & Kim, P. (2005) · Nature · doi:10.1038/nature04235 · Cited by 13,435
Berger, C., Song, Z., Li, T., Li, X., Ogbazghi, A. Y., Feng, R., Dai, Z., Marchenkov, A. N., Conrad, E. H., First, P. N., et al. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp040650f · Cited by 3,548
Cited by
Uniaxial Strain on Graphene: Raman Spectroscopy Study and Band-Gap Opening
Ni, Z. H., Yu, T., Lu, Y. H., Wang, Y. Y., Feng, Y. P., & Shen, Z. X. (2008) · ACS Nano · doi:10.1021/nn800459e · Cited by 1,627
Self-citationStructure of graphene and its disorders: a review
Yang, G., Li, L., Lee, W. B., & Ng, M. C. (2018) · Science and Technology of Advanced Materials · doi:10.1080/14686996.2018.1494493 · Cited by 759
Bioinspired mechano-photonic artificial synapse based on graphene/MoS 2 heterostructure
Yu, J., Yang, X., Gao, G., Xiong, Y., Wang, Y., Han, J., Chen, Y., Zhang, H., Sun, Q., & Wang, Z. L. (2021) · Science Advances · doi:10.1126/sciadv.abd9117 · Cited by 389
Self-citationLee, H. C., Liu, W.-W., Chai, S.-P., Mohamed, A. R., Aziz, A., Khe, C.-S., Hidayah, N. M. S., & Hashim, U. (2017) · RSC Advances · doi:10.1039/c7ra00392g · Cited by 357
Xu, P., Kang, J., Choi, J.-B., Suhr, J., Yu, J., Li, F., Byun, J.-H., Kim, B.-S., & Chou, T.-W. (2014) · ACS Nano · doi:10.1021/nn503570j · Cited by 266
Metadata
- Authors
- Wang, Y. Y., Ni, Z. H., Yu, T., Shen, Z. X., Wang, H. M., Wu, Y. H., Chen, W., & Shen Wee, A. T.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-06-26
- Volume
- 112
- Issue
- 29
- Pages
- 10637-10640
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2010191068
- Cited by
- 756
- References
- 4
- FWCI
- 13.47
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, Y. Y., Ni, Z. H., Yu, T., Shen, Z. X., Wang, H. M., Wu, Y. H., Chen, W., & Shen Wee, A. T. (2008). Raman Studies of Monolayer Graphene: The Substrate Effect. The Journal of Physical Chemistry C. https://doi.org/10.1021/jp8008404
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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