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Sculpturing Effect of Chloride Ions in Shape Transformation from Triangular to Discal Silver Nanoplates
Abstract
The sculpturing effect of chloride ions on the shape transformation of silver nanoparticles is presented. UV−vis spectroscopy and transmission electron microscopy (TEM) were used to monitor the evolution of silver nanoplates. Cl − can etch the corners and side faces of the silver nanoprism, and the resulting nanoparticles are disk-like in shape. The dissolved silver atoms would aggregate to form small silver clusters, which were stabilized by the Cl − and citrate ions. The facet-selective etching effect of Cl − is mainly attributed to the surface energy difference of each face of the nanoplate. The thickness of the nanodisk increased during the etching process because of the redeposition of sliver clusters on the {111} planes. The prepared nanodisk also gave rise to high SERS intensity of the probing molecule.
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Citations
Cites
Transmission Electron Microscopy of Shape-Controlled Nanocrystals and Their Assemblies
Wang, Z. L. (2000) · The Journal of Physical Chemistry B · doi:10.1021/jp993593c · Cited by 2,137
Cited by
Stability of Citrate, PVP, and PEG Coated Silver Nanoparticles in Ecotoxicology Media
Tejamaya, M., Römer, I., Merrifield, R. C., & Lead, J. R. (2012) · Environmental Science & Technology · doi:10.1021/es2038596 · Cited by 608
The Many “Facets” of Halide Ions in the Chemistry of Colloidal Inorganic Nanocrystals
Ghosh, S., & Manna, L. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00158 · Cited by 325
Fast and simple synthesis of triangular silver nanoparticles under the assistance of light
Nguyen, T. H. N., Nguyen, T. D., Cao, M. T., & Pham, V. V. (2020) · Colloids and Surfaces A: Physicochemical and Engineering Aspects · doi:10.1016/j.colsurfa.2020.124659 · Cited by 31
Metadata
- Authors
- An, J., Tang, B., Zheng, X., Zhou, J., Dong, F., Xu, S., Wang, Y., Zhao, B., & Xu, W.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-09-10
- Volume
- 112
- Issue
- 39
- Pages
- 15176-15182
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2085817975
- Cited by
- 207
- References
- 1
- FWCI
- 3.80
- Type
- journal article
- Language
- en
- Open access
- closed
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- An, J., Tang, B., Zheng, X., Zhou, J., Dong, F., Xu, S., Wang, Y., Zhao, B., & Xu, W. (2008). Sculpturing Effect of Chloride Ions in Shape Transformation from Triangular to Discal Silver Nanoplates. The Journal of Physical Chemistry C. https://doi.org/10.1021/jp802694p
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