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Sum Frequency Generation and Catalytic Reaction Studies of the Removal of Organic Capping Agents from Pt Nanoparticles by UV−Ozone Treatment

Aliaga, Cesar, Park, Jeong Y., Yamada, Yusuke, Lee, Hyun Sook, Tsung, Chia-Kuang, Yang, Peidong, Somorjai, Gabor A.·2009·The Journal of Physical Chemistry C

Abstract

We report the structure of the organic capping layers of platinum colloid nanoparticles and their removal by UV−ozone exposure. Sum frequency generation vibrational spectroscopy (SFGVS) studies identify the carbon−hydrogen stretching modes on poly(vinylpyrrolidone) (PVP) and tetradecyl tributylammonium bromide (TTAB)-capped platinum nanoparticles. We found that the UV−ozone treatment technique effectively removes the capping layer on the basis of several analytical measurements including SFGVS, X-ray photoelectron spectroscopy, and diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). The overall shape of the nanoparticles was preserved after the removal of capping layers, as confirmed by transmission electron microscopy (TEM). SFGVS of ethylene hydrogenation on the clean platinum nanoparticles demonstrates the existence of ethylidyne and di-σ-bonded species, indicating the similarity between single-crystal and nanoparticle systems.

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Metadata

Authors
Aliaga, C., Park, J. Y., Yamada, Y., Lee, H. S., Tsung, C.-K., Yang, P., & Somorjai, G. A.
Venue
The Journal of Physical Chemistry C
Published
2009-02-20
Volume
113
Issue
15
Pages
6150-6155
ISSN
  • 1932-7447 (ISSN-L)
  • 1932-7455
OpenAlex
W1978726185
Cited by
269
References
1
FWCI
7.54
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Sum Frequency Generation and Catalytic Reaction Studies of the Removal of Organic Capping Agents from Pt Nanoparticles by UV−Ozone Treatment. https://app.cochat.ai/papers/10.1021/jp8108946
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Aliaga, C., Park, J. Y., Yamada, Y., Lee, H. S., Tsung, C.-K., Yang, P., & Somorjai, G. A. (2009). Sum Frequency Generation and Catalytic Reaction Studies of the Removal of Organic Capping Agents from Pt Nanoparticles by UV−Ozone Treatment. The Journal of Physical Chemistry C. https://doi.org/10.1021/jp8108946

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