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Porphyrin and Fullerene Covalently Functionalized Graphene Hybrid Materials with Large Nonlinear Optical Properties

Liu, Zhi-Bo, Xu, Yan-Fei, Zhang, Xiao-Yan, Zhang, Xiao-Liang, Chen, Yong-Sheng, Tian, Jian-Guo·2009·The Journal of Physical Chemistry B

Abstract

The nonlinear optical properties of two novel graphene nanohybrid materials covalently functionalized with porphyrin and fullerene were investigated by using the Z-scan technique at 532 nm in the nanosecond and picosecond time scale. Results show that covalently functionalizing graphene with the reverse saturable absorption chromospheres porphyrin and fullerene can enhance the nonlinear optical performance in the nanosecond regime. The covalently linked graphene nanohybrids offer performance superior to that of the individual graphene, porphyrin, and fullerene by combination of a nonlinear mechanism and the photoinduced electron or energy transfer between porphyrin or fullerene moiety and graphene.

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Metadata

Authors
Liu, Z.-B., Xu, Y.-F., Zhang, X.-Y., Zhang, X.-L., Chen, Y.-S., & Tian, J.-G.
Venue
The Journal of Physical Chemistry B
Published
2009-07-01
Volume
113
Issue
29
Pages
9681-9686
ISSN
  • 1520-5207 (ISSN-L)
  • 1520-6106
OpenAlex
W1979761763
Cited by
466
References
0
FWCI
15.72
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Porphyrin and Fullerene Covalently Functionalized Graphene Hybrid Materials with Large Nonlinear Optical Properties. https://app.cochat.ai/papers/10.1021/jp9004357
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Liu, Z.-B., Xu, Y.-F., Zhang, X.-Y., Zhang, X.-L., Chen, Y.-S., & Tian, J.-G. (2009). Porphyrin and Fullerene Covalently Functionalized Graphene Hybrid Materials with Large Nonlinear Optical Properties. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp9004357

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