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Cited by 319

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Synthesis of CdS Nanorods by an Ethylenediamine Assisted Hydrothermal Method for Photocatalytic Hydrogen Evolution

Li, Yuexiang, Hu, Yuanfang, Peng, Shaoqin, Lu, Gongxuan, Li, Shuben·2009·The Journal of Physical Chemistry C

Abstract

CdS nanocrystals were synthesized by a hydrothermal method using ethylenediamine (en) as the template agent and coordination agent, and characterized by transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), BET, and UV−vis absorption spectroscopic techniques. Their photoactivity was evaluated by hydrogen evolution from aqueous solution containing formic acid as a hole scavenger under visible light (λ ≥ 420 nm) irradiation. The nanocrystals display rodlike and granular shapes, and their amount and morphology depend on the hydrothermal temperature and the added content of en. Photoactivity of the nanorods is higher than that of the nanograins. The effect of deposited Pt as cocatalyst on photoactivity for hydrogen evolution has been investigated. Pt can be dispersed highly on CdS so that the Pt content for effective hydrogen evolution is very low. 0.050 wt % Pt-loaded CdS shows the highest activity for hydrogen evolution under visible light irradiation, and the apparent quantum yield amounts to 13.9%. A possible mechanism was discussed.

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Metadata

Authors
Li, Y., Hu, Y., Peng, S., Lu, G., & Li, S.
Venue
The Journal of Physical Chemistry C
Published
2009-04-30
Volume
113
Issue
21
Pages
9352-9358
ISSN
  • 1932-7447 (ISSN-L)
  • 1932-7455
OpenAlex
W2028724796
Cited by
319
References
1
FWCI
8.57
Type
journal article
Language
en
Open access
closed

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