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Hybrid Anion and Proton Exchange Membrane Fuel Cells
Abstract
A novel hybrid fuel cell is described using at least one electrode operating at high pH in an effort to use the high conductivity of Nafion and exploit the electrochemical advantages of high-pH operation. The electrochemical behavior of a hybrid anion exchange membrane (AEM)/proton exchange membrane (PEM) junction and corresponding fuel cell are presented. Two AEM/PEM junctions and fuel cells have been evaluated: AEM anode/PEM cathode and PEM anode/AEM cathode. The AEM cathode/PEM membrane configuration causes proton−hydroxide recombination at the membrane junction, resulting in self-hydration of the membrane. The fuel cell performance improves at lower relative humidity. At 65 °C and 0% relative humidity, the hybrid cell operates at steady state whereas the performance of a conventional PEM cell decreases with time due to dry-out.
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Cited by
Anion-exchange membranes in electrochemical energy systems
Varcoe, J. R., Atanassov, P., Dekel, D. R., Herring, A. M., Hickner, M. A., Kohl, P. A., Kucernak, A. R., Mustain, W. E., Nijmeijer, K., Scott, K., et al. (2014) · Energy Environ. Sci. · doi:10.1039/c4ee01303d · Cited by 2,051
Self-citationInsights and Challenges for Applying Bipolar Membranes in Advanced Electrochemical Energy Systems
Blommaert, M. A., Aili, D., Tufa, R. A., Li, Q., Smith, W. A., & Vermaas, D. A. (2021) · ACS Energy Letters · doi:10.1021/acsenergylett.1c00618 · Cited by 253
Sun, K., Liu, R., Chen, Y., Verlage, E., Lewis, N. S., & Xiang, C. (2016) · Advanced Energy Materials · doi:10.1002/aenm.201600379 · Cited by 139
McDonald, M. B., Ardo, S., Lewis, N. S., & Freund, M. S. (2014) · ChemSusChem · doi:10.1002/cssc.201402288 · Cited by 128
Reiter, R. S., White, W., & Ardo, S. (2016) · Journal of The Electrochemical Society · doi:10.1149/2.0201604jes · Cited by 49
Metadata
- Authors
- Ünlü, M., Zhou, J., & Kohl, P. A.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-06-04
- Volume
- 113
- Issue
- 26
- Pages
- 11416-11423
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2081305290
- Cited by
- 168
- References
- 0
- FWCI
- 5.54
- Type
- journal article
- Language
- en
- Open access
- closed
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- Ünlü, M., Zhou, J., & Kohl, P. A. (2009). Hybrid Anion and Proton Exchange Membrane Fuel Cells. The Journal of Physical Chemistry C. https://doi.org/10.1021/jp903252u
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