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Cited by 555

The DOI matches its Crossref record; 27 of the 27 references it cites were found in a registry or an index.

Visible Light-Driven Photocatalytic Degradation of Rhodamine B over NaBiO3: Pathways and Mechanism

Yu, Kai, Yang, Shaogui, He, Huan, Sun, Cheng, Gu, Chenggang, Ju, Yongming·2009·The Journal of Physical Chemistry A

Abstract

The photocatalytic degradation of rhodamine B (RhB) over NaBiO3 under visible light irradiation was investigated in this study. RhB (20 mg/L) was almost completely decolorized in 30 min in given conditions. It was found that catalyst heating temperature significantly influenced the photocatalytic activity of the catalyst in which crystal water may played an important role, and the original sample exhibited higher activity than the heated samples did. To scrutinize the mechanistic details of the dye photodegradation, several critical analytical methods including UV-vis spectroscopy, HPLC, LC/MS/MS, and GC/MS were utilized to monitor the temporal course of the reaction. All N-deethylation intermediates and several small molecular products were separated and identified. The yield distinctness between two isomer intermediates (DR and EER) was considered to be correlated with the changes in the electron density of the dye molecule. Then two possible competitive photodegradation pathways of RhB over NaBiO3 were proposed: Chromophore cleavage and N-deethylation. Yet, cleavage of dye chromophore structure predominated over the N-deethylation.

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Metadata

Authors
Yu, K., Yang, S., He, H., Sun, C., Gu, C., & Ju, Y.
Venue
The Journal of Physical Chemistry A
Published
2009-08-25
Volume
113
Issue
37
Pages
10024-10032
ISSN
  • 1089-5639 (ISSN-L)
  • 1520-5215
OpenAlex
W2070065499
Cited by
555
References
27
FWCI
5.14
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Visible Light-Driven Photocatalytic Degradation of Rhodamine B over NaBiO3: Pathways and Mechanism. https://app.cochat.ai/papers/10.1021/jp905173e
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Yu, K., Yang, S., He, H., Sun, C., Gu, C., & Ju, Y. (2009). Visible Light-Driven Photocatalytic Degradation of Rhodamine B over NaBiO3: Pathways and Mechanism. The Journal of Physical Chemistry A. https://doi.org/10.1021/jp905173e

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