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Magnetite Decorated Multiwalled Carbon Nanotube Based Supercapacitor for Arsenic Removal and Desalination of Seawater
Abstract
A new type of flexible carbon fabric supported magnetite multiwalled carbon nanotubes (Fe 3 O 4 -MWNTs) nanocomposite based supercapacitor was fabricated for the removal of high concentration of arsenic and desalination of seawater. MWNTs were synthesized by a chemical vapor deposition (CVD) technique, purified by air oxidation and acid treatment followed by further functionalization. Decoration of magnetite (Fe 3 O 4 ) nanoparticles over functionalized MWNTs surface was done by a chemical technique. Fe 3 O 4 -MWNTs nanocomposite was characterized using different characterization techniques. Electrochemical activity of the nanocomposite was analyzed for arsenite and arsenate ions containing water as well as for seawater by using cyclic voltametry (CV). Adsorption isotherms and kinetic characteristics of sodium, arsenate, and arsenite ion removal were studied. Performance of the filter made up of nanocomposite-based electrodes was examined by an inductive coupled plasma optical emission spectroscopy (ICP-OES) technique. The present study shows the novel nature of the nanocomposite, which can remove both types of arsenic ions (arsenate and arsenite) and salt from seawater. High desalination efficiency (removal of sodium, magnesium, and calcium) of seawater and repeatability for the simultaneous removal of arsenic (both arsenate and arsenite) and sodium have been demonstrated in the present work.
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Cites
Critical review in adsorption kinetic models
Qiu, H., Lv, L., Pan, B.-C., Zhang, Q.-J., Zhang, W.-M., & Zhang, Q.-X. (2009) · Journal of Zhejiang University-SCIENCE A · doi:10.1631/jzus.a0820524 · Cited by 1,776
Cited by
Xu, J., Cao, Z., Zhang, Y., Yuan, Z., Lou, Z., Xu, X., & Wang, X. (2018) · Chemosphere · doi:10.1016/j.chemosphere.2017.12.061 · Cited by 786
Ai, L., Zhang, C., & Chen, Z. (2011) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2011.06.068 · Cited by 771
Ai, L., Zhang, C., Liao, F., Wang, Y., Li, M., Meng, L., & Jiang, J. (2011) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2011.10.041 · Cited by 737
Qu, Q., Yang, S., & Feng, X. (2011) · Advanced Materials · doi:10.1002/adma.201103042 · Cited by 577
Graphene Oxide–MnFe2O4 Magnetic Nanohybrids for Efficient Removal of Lead and Arsenic from Water
Kumar, S., Nair, R. R., Pillai, P. B., Gupta, S. N., Iyengar, M. A. R., & Sood, A. K. (2014) · ACS Applied Materials & Interfaces · doi:10.1021/am504826q · Cited by 573
Metadata
- Authors
- Mishra, A. K., & Ramaprabhu, S.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-01-27
- Volume
- 114
- Issue
- 6
- Pages
- 2583-2590
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W1989633796
- Cited by
- 177
- References
- 1
- FWCI
- 11.13
- Type
- journal article
- Language
- en
- Open access
- closed
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- Mishra, A. K., & Ramaprabhu, S. (2010). Magnetite Decorated Multiwalled Carbon Nanotube Based Supercapacitor for Arsenic Removal and Desalination of Seawater. The Journal of Physical Chemistry C. https://doi.org/10.1021/jp911631w
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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