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Cited by 267

The DOI matches its Crossref record; 31 of the 31 references it cites were found in a registry or an index.

Curve Crossing Formulation for Proton Transfer Reactions in Solution

Borgis, Daniel, Hynes, James T.·1996·The Journal of Physical Chemistry
DOI 10.1021/jp9522324
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Abstract

A Landau−Zener curve crossing formulation is developed for proton transfer rate constants over the range of proton coupling. This approach spans the weak coupling regime, where the transfer is a nonadiabatic proton tunneling, to the strong coupling regime, where at the reaction transition state the proton motion is a quantized vibration lying above the barrier in the proton coordinate. The theory requires that there is strong coupling of the proton transfer solute to the surrounding polar solvent and includes the influence of the vibrational motion of the heavy particles between which the proton transfers. Analytic formulas are given for the rate constants in various limits of the proton coupling strength and the vibrational frequency of the heavy particle motion.

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Metadata

Authors
Borgis, D., & Hynes, J. T.
Venue
The Journal of Physical Chemistry
Publisher
American Chemical Society (ACS)
Published
1996-01-01
Volume
100
Issue
4
Pages
1118-1128
ISSN
  • 0022-3654 (ISSN-L)
  • 1541-5740
DOI
10.1021/jp9522324
OpenAlex
W1970327813
Cited by
267
References
31
FWCI
6.40
Type
journal article
Language
en
Open access
closed

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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