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Temperature Dependence of Oxygen Diffusion in H2O and D2O
Abstract
The diffusion coefficient of O 2 in H 2 O and D 2 O has been determined as a function of temperature from −0.5 to 95 °C, using the Taylor dispersion technique with optical absorbance detection at 200 nm. Over this temperature range, significant deviation from both Arrhenius and Stokes−Einstein behavior is found. A practical interpolation formula for the H 2 O solvent is ( T in Kelvin) log 10 [ D /cm 2 s -1 ] = −4.410 + 773.8/ T − (506.4/ T ) 2 and, for the D 2 O solvent, log 10 [ D /cm 2 s -1 ] = −4.706 + 903.6/ T − (526.6/ T ) 2 . As a test of the apparatus, the diffusion coefficient of nitrobenzene in water was carefully measured and found to be 1.04 × 10 -5 cm 2 s -1 at 26 °C and 2.14 × 10 -5 cm 2 s -1 at 60.1 °C.
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Metadata
- Authors
- Han, P., & Bartels, D. M.
- Venue
- The Journal of Physical Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 1996-01-01
- Volume
- 100
- Issue
- 13
- Pages
- 5597-5602
- ISSN
- 0022-3654 (ISSN-L)
- 1541-5740
- OpenAlex
- W2036965645
- Cited by
- 363
- References
- 0
- FWCI
- 0.48
- Type
- journal article
- Language
- en
- Open access
- closed
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- Han, P., & Bartels, D. M. (1996). Temperature Dependence of Oxygen Diffusion in H2O and D2O. The Journal of Physical Chemistry. https://doi.org/10.1021/jp952903y
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