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Solid-State NMR Studies of the Structure of Graphite Oxide
Abstract
Graphite oxide (GO) and its derivatives have been studied using 13 C and 1 H NMR. The 13 C NMR lines at 60, 70, and 130 ppm are assigned to C−OH, C−O−C, and >C C< groups in the bulk of the material, respectively. The >C C< double bonds are relatively stable, while C−OH groups may condense to form C−O−C (ether) linkages. There are at least two magnetically inequivalent C−OH sites, and the structure does not necessarily possess long-range order. Water molecules interact very strongly with the structure. The results reveal a number of new structural features.
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Citations
Cited by
The chemistry of graphene oxide
Dreyer, D. R., Park, S., Bielawski, C. W., & Ruoff, R. S. (2010) · Chem. Soc. Rev. · doi:10.1039/b917103g · Cited by 11,653
Graphene oxide incorporated functional materials: A review
Ahmad, H., Fan, M., & Hui, D. (2018) · Composites Part B: Engineering · doi:10.1016/j.compositesb.2018.02.006 · Cited by 315
Li, M.-J., Liu, C.-M., Xie, Y.-B., Cao, H.-B., Zhao, H., & Zhang, Y. (2014) · Carbon · doi:10.1016/j.carbon.2013.09.004 · Cited by 202
Metadata
- Authors
- He, H., Riedl, T., Lerf, A., & Klinowski, J.
- Venue
- The Journal of Physical Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 1996-01-01
- Volume
- 100
- Issue
- 51
- Pages
- 19954-19958
- ISSN
- 0022-3654 (ISSN-L)
- 1541-5740
- OpenAlex
- W2036639991
- Cited by
- 441
- References
- 0
- FWCI
- 1.35
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
