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Highly Oriented Molecular Ag Nanocrystal Arrays
Abstract
Orientational ordering of faceted nanocrystals in nanocrystal arrays has been directly observed for the first time, by use of transmission electron microscopy imaging and diffraction to resolve the structure of thin molecular-crystalline films of silver nanocrystals passivated by alkylthiolate self-assembled monolayers. The type of ordering found is determined by the nanocrystal’s faceted morphology, as mediated by the interactions of surfactant groups tethered to the facets on neighboring nanocrystals. Orientational ordering is crucial for the understanding of the fundamental properties of quantum-dot arrays, as well as for their optimal utilization in optical and electronic applications.
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Citations
Cited by
Synthesis and Characterization of Monodisperse Nanocrystals and Close-Packed Nanocrystal Assemblies
Murray, C. B., Kagan, C. R., & Bawendi, M. G. (2000) · Annual Review of Materials Science · doi:10.1146/annurev.matsci.30.1.545 · Cited by 4,353
Transmission Electron Microscopy of Shape-Controlled Nanocrystals and Their Assemblies
Wang, Z. L. (2000) · The Journal of Physical Chemistry B · doi:10.1021/jp993593c · Cited by 2,137
Self-citationDrying-Mediated Self-Assembly of Nanoparticles
Rabani, E., Reichman, D. R., Geissler, P. L., & Brus, L. E. (2003) · Nature · doi:10.1038/nature02087 · Cited by 913
Synthesis, structure and properties of metal nanoclusters
Wilcoxon, J. P., & Abrams, B. L. (2006) · Chemical Society Reviews · doi:10.1039/b517312b · Cited by 760
Crystal Structures of Molecular Gold Nanocrystal Arrays
Whetten, R. L., Shafigullin, M. N., Khoury, J. T., Schaaff, T. G., Vezmar, I., Alvarez, M. M., & Wilkinson, A. (1999) · Accounts of Chemical Research · doi:10.1021/ar970239t · Cited by 580
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Metadata
- Authors
- Harfenist, S. A., Wang, Z. L., Alvarez, M. M., Vezmar, I., & Whetten, R. L.
- Venue
- The Journal of Physical Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 1996-01-01
- Volume
- 100
- Issue
- 33
- Pages
- 13904-13910
- ISSN
- 0022-3654 (ISSN-L)
- 1541-5740
- OpenAlex
- W2135426122
- Cited by
- 381
- References
- 0
- FWCI
- 27.02
- Type
- journal article
- Language
- en
- Open access
- closed
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- Harfenist, S. A., Wang, Z. L., Alvarez, M. M., Vezmar, I., & Whetten, R. L. (1996). Highly Oriented Molecular Ag Nanocrystal Arrays. The Journal of Physical Chemistry. https://doi.org/10.1021/jp961764x
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