The DOI matches its Crossref record; 10 of the 10 references it cites were found in a registry or an index.
Effect of Hydrophobic Chain Length of Surfactants on Enthalpy−Entropy Compensation of Micellization
Abstract
It is well-known that there exists a minimum critical micelle concentration (cmc) in the cmc−temperature curve. It is found that the temperature of minimum cmc, T min, for both nonionic and ionic surfactants increases as the hydrophobicity of surfactants decreases. The temperature dependence of cmc is used to calculate the enthalpies and entropies of micelle formation for six different homologous series of surfactants. The enthalpy−entropy compensation plot exhibits an excellent linearity. It is found that all the compensation lines for surfactants in a homologous series are parallel to one another and the intercept of these compensation lines is a linear function of the hydrophobic chain length of surfactants.
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Cites
Surfactants and interfacial phenomena
Silberberg, A. (1990) · Journal of Colloid and Interface Science · doi:10.1016/0021-9797(90)90169-o · Cited by 1,437
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The energetics of micelle formation
Phillips, J. N. (1955) · Transactions of the Faraday Society · doi:10.1039/tf9555100561 · Cited by 588
CONDUCTIVITY OF AQUEOUS SOLUTIONS OF SOME PARAFFIN CHAIN SALTS
Goddard, E. D., & Benson, G. C. (1957) · Canadian Journal of Chemistry · doi:10.1139/v57-134 · Cited by 200
The effect of temperature on the critical micelle concentration of some paraffin-chain salts
Flockhart, B. D. (1961) · Journal of Colloid Science · doi:10.1016/0095-8522(61)90026-5 · Cited by 166
The heats of micelle formation of sodium dodecyl sulphate
Matijevi, E., & Pethica, B. A. (1958) · Transactions of the Faraday Society · doi:10.1039/tf9585400587 · Cited by 104
Evans, D. F., & Wightman, P. J. (1982) · Journal of Colloid and Interface Science · doi:10.1016/0021-9797(82)90096-0 · Cited by 96
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Cited by
Amphiphile nanoarchitectonics: from basic physical chemistry to advanced applications
Ramanathan, M., Shrestha, L. K., Mori, T., Ji, Q., Hill, J. P., & Ariga, K. (2013) · Physical Chemistry Chemical Physics · doi:10.1039/c3cp50620g · Cited by 353
Langridge, T. D., & Gemeinhart, R. A. (2020) · Journal of Controlled Release · doi:10.1016/j.jconrel.2019.12.038 · Cited by 51
Metadata
- Authors
- Chen, L.-J., Lin, S.-Y., & Huang, C.-C.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 1998-05-01
- Volume
- 102
- Issue
- 22
- Pages
- 4350-4356
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2059560778
- Cited by
- 353
- References
- 10
- FWCI
- 3.03
- Type
- journal article
- Language
- en
- Open access
- closed
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- Chen, L.-J., Lin, S.-Y., & Huang, C.-C. (1998). Effect of Hydrophobic Chain Length of Surfactants on Enthalpy−Entropy Compensation of Micellization. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp9804345
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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