The DOI matches its Crossref record.
Anisotropic Photochemical Reactivity of Bulk TiO2 Crystals
Abstract
Polished and annealed surfaces of randomly textured rutile polycrystals were used to photochemically reduce Ag + to Ag metal in an aqueous solution. By correlating the surface orientations of more than 100 individual crystallites with the amount of deposited Ag, we conclude that the most reactive orientations lie near the {101} plane. Most annealed rutile surfaces are microscopically faceted so that they locally expose planes that are not parallel to the crystallite's average surface. The observations reported here indicate that the anisotropy of rutile's photochemical properties derives from differences in the properties of specific surface planes rather than the bulk crystallite orientation.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
TiO2 photocatalysis and related surface phenomena
FUJISHIMA, A., ZHANG, X., & TRYK, D. (2008) · Surface Science Reports · doi:10.1016/j.surfrep.2008.10.001 · Cited by 6,737
Surface Science Studies of the Photoactivation of TiO 2 New Photochemical Processes
Thompson, T. L., & Yates, J. T. (2006) · Chemical Reviews · doi:10.1021/cr050172k · Cited by 2,064
Why is anatase a better photocatalyst than rutile? - Model studies on epitaxial TiO2 films
Luttrell, T., Halpegamage, S., Tao, J., Kramer, A., Sutter, E., & Batzill, M. (2014) · Scientific Reports · doi:10.1038/srep04043 · Cited by 1,544
Mechanistic Insight into the TiO2Photocatalytic Reactions: Design of New Photocatalysts
Tachikawa, T., Fujitsuka, M., & Majima, T. (2007) · The Journal of Physical Chemistry C · doi:10.1021/jp069005u · Cited by 668
Trends in the Hydrogen Evolution Activity of Metal Carbide Catalysts
Michalsky, R., Zhang, Y.-J., & Peterson, A. A. (2014) · ACS Catalysis · doi:10.1021/cs500056u · Cited by 406
Metadata
- Authors
- Lowekamp, J. B., Rohrer, G. S., Morris Hotsenpiller, P. A., Bolt, J. D., & Farneth, W. E.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 1998-08-29
- Volume
- 102
- Issue
- 38
- Pages
- 7323-7327
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W1982835583
- Cited by
- 173
- References
- 0
- FWCI
- 4.69
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Anisotropic Photochemical Reactivity of Bulk TiO2 Crystals. https://app.cochat.ai/papers/10.1021/jp982721e
- The paper
- Lowekamp, J. B., Rohrer, G. S., Morris Hotsenpiller, P. A., Bolt, J. D., & Farneth, W. E. (1998). Anisotropic Photochemical Reactivity of Bulk TiO2 Crystals. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp982721e
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
