The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Physisorption of Hydrogen on Microporous Carbon and Carbon Nanotubes
Abstract
We have investigated the storage capability of microporous carbon materials for gaseous hydrogen both theoretically and experimentally. In the grand canonical Monte Carlo calculation the hydrogen molecules are physisorbed by van der Waals interactions with the surface atoms of carbon slitpores and carbon nanotubes. At room temperature the optimum pore geometry is a slitpore consisting of two graphite platelets separated by a distance that corresponds approximately to two times the diameter of a hydrogen molecule. In this case for a storage pressure of 10 MPa a maximum adsorbed hydrogen density of 14 kg/m 3 can be reached, which corresponds to a gravimetric storage capacity of 1.3 wt %. Only for low gas pressure a cylindrical geometry like that in carbon nanotubes can exceed the storage density of carbon slitpores owing to capillary forces.
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Cites
Storage of hydrogen in single-walled carbon nanotubes
Dillon, A. C., Jones, K. M., Bekkedahl, T. A., Kiang, C. H., Bethune, D. S., & Heben, M. J. (1997) · Nature · doi:10.1038/386377a0 · Cited by 3,802
The interaction of gases with solid surfaces
Steele, W. A. (1974) · CERN Document Server (European Organization for Nuclear Research) · Cited by 1,504
Hydrogen Storage in Graphite Nanofibers
Chambers, A., Park, C., Baker, R. T. K., & Rodriguez, N. M. (1998) · The Journal of Physical Chemistry B · doi:10.1021/jp980114l · Cited by 959
Methane adsorption on microporous carbons—A comparison of experiment, theory, and simulation
Aukett, P. N., Quirke, N., Riddiford, S. M., & Tennison, S. R. (1992) · Carbon · doi:10.1016/0008-6223(92)90015-o · Cited by 147
Effect of the activating gas on tensile strength and pore structure of pitch-based carbon fibres
Alcañiz-Monge, J., Cazorla‐Amorós, D., Linares-Solano, A., Yoshida, S., & Ōya, A. (1994) · Carbon · doi:10.1016/0008-6223(94)90113-9 · Cited by 140
Cited by
Hydrogen storage in metal–organic frameworks
Murray, L. J., Dincă, M., & Long, J. R. (2009) · Chemical Society Reviews · doi:10.1039/b802256a · Cited by 4,532
Materials for hydrogen storage
Züttel, A. (2003) · Materials Today · doi:10.1016/s1369-7021(03)00922-2 · Cited by 2,216
Rao, C. N. R., Satishkumar, B. C., Govindaraj, A., & Nath, M. (2001) · ChemPhysChem · doi:10.1002/1439-7641(20010216)2:2<78::aid-cphc78>3.0.co;2-7 · Cited by 586
Flexibility in metal-organic framework materials: Impact on sorption properties
Fletcher, A. J., Thomas, K. M., & Rosseinsky, M. J. (2005) · Journal of Solid State Chemistry · doi:10.1016/j.jssc.2005.05.019 · Cited by 543
Hydrogen storage: beyond conventional methods
Dalebrook, A. F., Gan, W., Grasemann, M., Moret, S., & Laurenczy, G. (2013) · Chemical Communications · doi:10.1039/c3cc43836h · Cited by 503
Metadata
- Authors
- Rzepka, M., Lamp, P., & de la Casa-Lillo, M. A.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 1998-12-01
- Volume
- 102
- Issue
- 52
- Pages
- 10894-10898
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W1982055098
- Cited by
- 558
- References
- 5
- FWCI
- 9.99
- Type
- journal article
- Language
- en
- Open access
- closed
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