Student or educator? Sign up with your school email and get 6 months of Pro free.
CoChat
Sign Up
Cited by 161

The DOI matches its Crossref record.

Study of Interfacial Charge-Transfer Complex on TiO2 Particles in Aqueous Suspension by Second-Harmonic Generation

Liu, Yan, Dadap, J. I., Zimdars, David, Eisenthal, Kenneth B.·1999·The Journal of Physical Chemistry B
DOI 10.1021/jp984288e
Open this paper in CoChat — free account

Abstract

We report the first direct observation of an interfacial charge-transfer complex using second-harmonic spectroscopy. The second-harmonic spectrum of catechol adsorbed on 0.4 micron-sized TiO 2 (anatase) colloidal particles in aqueous suspension reveals a charge-transfer band centered at 2.72 eV (456 nm). In addition, the adsorption isotherm of catechol on the colloidal TiO 2 suspension was obtained and gave an excellent fit to the Langmuir adsorption model. From this, we infer the free energy of the adsorption to be Δ G ° = −6.8 kcal/mol.

Overview

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Integrity signals

Registry

Crossref · 10.1021/jp984288e

Cites

Statistics

Verification

Claims the paper makes

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

The self-check needs the paper’s full text.

Citations

Cited by

See all 161

Metadata

Authors
Liu, Y., Dadap, J. I., Zimdars, D., & Eisenthal, K. B.
Venue
The Journal of Physical Chemistry B
Publisher
American Chemical Society (ACS)
Published
1999-03-12
Volume
103
Issue
13
Pages
2480-2486
ISSN
  • 1520-5207 (ISSN-L)
  • 1520-6106
DOI
10.1021/jp984288e
OpenAlex
W2025363014
Cited by
161
References
0
FWCI
9.61
Type
journal article
Language
en
Open access
closed

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

How to cite

Cite CoChat for the checks on this page, and the paper for its own findings.

This page
CoChat. (2026). Citation check: Study of Interfacial Charge-Transfer Complex on TiO2 Particles in Aqueous Suspension by Second-Harmonic Generation. https://app.cochat.ai/papers/10.1021/jp984288e
The paper
Liu, Y., Dadap, J. I., Zimdars, D., & Eisenthal, K. B. (1999). Study of Interfacial Charge-Transfer Complex on TiO2 Particles in Aqueous Suspension by Second-Harmonic Generation. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp984288e

Data sources

Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.