The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Enhanced Adsorption of Molecules on Surfaces of Nanocrystalline Particles
Abstract
Quantitative measurements of adsorption from solution show up to a 70-fold increase in the adsorption coefficient when a variety of organic acids are adsorbed onto 6 nm compared to 16 nm nanocrystalline titania particles. A Langmuir adsorption model modified to include the dependence of interfacial tension (interfacial free energy) on particle size predicts an increase in the adsorption constant ( K ads ) as the crystallite size decreases, in agreement with the experimental results. The increase in K ads arises predominantly from the increased molar surface free energy of the nanocrystalline particles. The rapid increase in adsorption as particle size decreases has important implications for understanding and modeling natural and experimental systems.
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Citations
Cites
Stark, J. V., Park, D. G., Lagadic, I., & Klabunde, K. J. (1996) · Chemistry of Materials · doi:10.1021/cm950583p · Cited by 210
Cited by
Ghosh, S. K., & Pal, T. (2007) · Chemical Reviews · doi:10.1021/cr0680282 · Cited by 2,782
The Effect of Size-Dependent Nanoparticle Energetics on Catalyst Sintering
Campbell, C. T., Parker, S. C., & Starr, D. E. (2002) · Science · doi:10.1126/science.1075094 · Cited by 1,050
French, R. A., Jacobson, A. R., Kim, B., Isley, S. L., Penn, R. L., & Baveye, P. C. (2009) · Environmental Science & Technology · doi:10.1021/es802628n · Cited by 788
Self-citationWaychunas, G. A., Kim, C. S., & Banfield, J. F. (2005) · Journal of Nanoparticle Research · doi:10.1007/s11051-005-6931-x · Cited by 616
Self-citationSize effect of polystyrene microplastics on sorption of phenanthrene and nitrobenzene
Wang, J., Liu, X., Liu, G., Zhang, Z., Wu, H., Cui, B., Bai, J., & Zhang, W. (2019) · Ecotoxicology and Environmental Safety · doi:10.1016/j.ecoenv.2019.02.037 · Cited by 319
Metadata
- Authors
- Zhang, H., Penn, R. L., Hamers, R. J., & Banfield, J. F.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 1999-05-07
- Volume
- 103
- Issue
- 22
- Pages
- 4656-4662
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W1999897987
- Cited by
- 261
- References
- 1
- FWCI
- 2.77
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
