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Near-Infrared Luminescence from Small Gold Nanocrystals
Abstract
A novel photoluminescence is reported for small metal nanocrystals in the near-infrared region (1.1−1.6 μm). Near-infrared photoluminescence spectra were measured at room temperature for 1.1 and 1.7 nm Au nanocrystals using a 1.06 μm excitation source. This photoluminescence is attributed to sp to sp-like transitions, analogous to intraband transitions in bulk gold; however, the exact mechanism is unknown. A conservative estimate for the quantum yield for the 1.7 nm gold nanocrystals is (4.4 ± 1.5) × 10 -5 at room temperature, more than 5 orders of magnitude greater than that of bulk gold.
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Citations
Cited by
Negishi, Y., Nobusada, K., & Tsukuda, T. (2005) · Journal of the American Chemical Society · doi:10.1021/ja042218h · Cited by 1,646
Sub-nanometre sized metal clusters: from synthetic challenges to the unique property discoveries
Lu, Y., & Chen, W. (2012) · Chemical Society Reviews · doi:10.1039/c2cs15325d · Cited by 1,152
A Review on the Synthesis and Functionalization of Gold Nanoparticles as a Drug Delivery Vehicle
Amina, S. J., & Guo, B. (2020) · International Journal of Nanomedicine · doi:10.2147/ijn.s279094 · Cited by 561
Wei, W., Lu, Y., Chen, W., & Chen, S. (2011) · Journal of the American Chemical Society · doi:10.1021/ja109303z · Cited by 481
Luminescent Noble Metal Nanoclusters as an Emerging Optical Probe for Sensor Development
Yuan, X., Luo, Z., Yu, Y., Yao, Q., & Xie, J. (2013) · Chemistry – An Asian Journal · doi:10.1002/asia.201201236 · Cited by 328
Metadata
- Authors
- Bigioni, T. P., Whetten, R. L., & Dag, Ö.
- Venue
- The Journal of Physical Chemistry B
- Publisher
- American Chemical Society (ACS)
- Published
- 2000-07-06
- Volume
- 104
- Issue
- 30
- Pages
- 6983-6986
- ISSN
- 1520-5207 (ISSN-L)
- 1520-6106
- OpenAlex
- W2064474620
- Cited by
- 282
- References
- 0
- FWCI
- 5.07
- Type
- journal article
- Language
- en
- Open access
- closed
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- Bigioni, T. P., Whetten, R. L., & Dag, Ö. (2000). Near-Infrared Luminescence from Small Gold Nanocrystals. The Journal of Physical Chemistry B. https://doi.org/10.1021/jp993867w
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