The DOI matches its Crossref record; 24 of the 24 references it cites were found in a registry or an index.
Investigation of Catalytic Finite-Size-Effects of Platinum Metal Clusters
Abstract
In this paper, we use density functional theory (DFT) calculations on highly parallel computing resources to study size-dependent changes in the chemical and electronic properties of platinum (Pt) for a number of fixed freestanding clusters ranging from 13 to 1415 atoms, or 0.7-3.5 nm in diameter. We find that the surface catalytic properties of the clusters converge to the single crystal limit for clusters with as few as 147 atoms (1.6 nm). Recently published results for gold (Au) clusters showed analogous convergence with size. However, this convergence happened at larger sizes, because the Au d-states do not contribute to the density of states around the Fermi-level, and the observed level fluctuations were not significantly damped until the cluster reached ca. 560 atoms (2.7 nm) in size.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Hammer, B., Hansen, L. B., & Nørskov, J. K. (1999) · Physical Review B · doi:10.1103/physrevb.59.7413 · Cited by 8,270
Self-citationImproved tetrahedron method for Brillouin-zone integrations
Blöchl, P. E., Jepsen, O., & Andersen, O. K. (1994) · Physical Review B · doi:10.1103/physrevb.49.16223 · Cited by 7,297
Alloys of platinum and early transition metals as oxygen reduction electrocatalysts
Greeley, J., Stephens, I. E. L., Bondarenko, A. S., Johansson, T. P., Hansen, H. A., Jaramillo, T. F., Rossmeisl, J., Chorkendorff, I., & Nørskov, J. K. (2009) · Nature Chemistry · doi:10.1038/nchem.367 · Cited by 3,203
Self-citationElectronic factors determining the reactivity of metal surfaces
Hammer, B., & Nørskov, J. K. (1995) · Surface Science · doi:10.1016/0039-6028(96)80007-0 · Cited by 2,871
Self-citationEffect of Strain on the Reactivity of Metal Surfaces
Mavrikakis, M., Hammer, B., & Nørskov, J. K. (1998) · Physical Review Letters · doi:10.1103/physrevlett.81.2819 · Cited by 2,380
Self-citationEnkovaara, J., Rostgaard, C., Mortensen, J. J., Chen, J., Dułak, M., Ferrighi, L., Gavnholt, J., Glinsvad, C., Haikola, V, Hansen, H. A., et al. (2010) · Journal of Physics: Condensed Matter · doi:10.1088/0953-8984/22/25/253202 · Cited by 2,208
Self-citationReal-space grid implementation of the projector augmented wave method
Mortensen, J. J., Hansen, L. B., & Jacobsen, K. W. (2005) · Physical Review B · doi:10.1103/physrevb.71.035109 · Cited by 2,072
Self-citationThe physics of simple metal clusters: self-consistent jellium model and semiclassical approaches
Brack, M. (1993) · Reviews of Modern Physics · doi:10.1103/revmodphys.65.677 · Cited by 1,696
Abild-Pedersen, F., Greeley, J., Studt, F., Rossmeisl, J., Munter, T. R., Moses, P. G., Skúlason, E., Bligaard, T., & Nørskov, J. K. (2007) · Physical Review Letters · doi:10.1103/physrevlett.99.016105 · Cited by 1,678
Self-citationRuban, A., Hammer, B., Stoltze, P., Skriver, H. L., & Nørskov, J. K. (1997) · Journal of Molecular Catalysis A: Chemical · doi:10.1016/s1381-1169(96)00348-2 · Cited by 1,370
Self-citationChemisorption of CO on the Pt(111) surface
Ertl, G., Neumann, M., & Streit, K. M. (1977) · Surface Science · doi:10.1016/0039-6028(77)90052-8 · Cited by 815
Nørskov, J. K. (1982) · Physical Review B · doi:10.1103/physrevb.26.2875 · Cited by 462
Self-citationInsights into the reactivity of supported Au nanoparticles: combining theory and experiments
Janssens, T. V. W., Clausen, B. S., Hvolbæk, B., Falsig, H., Christensen, C. H., Bligaard, T., & Nørskov, J. K. (2007) · Topics in Catalysis · doi:10.1007/s11244-007-0335-3 · Cited by 437
Self-citationTrends in CO Oxidation Rates for Metal Nanoparticles and Close-Packed, Stepped, and Kinked Surfaces
Jiang, T., Mowbray, D. J., Dobrin, S., Falsig, H., Hvolbæk, B., Bligaard, T., & Nørskov, J. K. (2009) · The Journal of Physical Chemistry C · doi:10.1021/jp811185g · Cited by 276
Self-citationFinite Size Effects in Chemical Bonding: From Small Clusters to Solids
Kleis, J., Greeley, J., Romero, N. A., Morozov, V. A., Falsig, H., Larsen, A. H., Lu, J., Mortensen, J. J., Dułak, M., Thygesen, K. S., et al. (2011) · Catalysis Letters · doi:10.1007/s10562-011-0632-0 · Cited by 270
Self-citationH2‐Induced Reconstruction of Supported Pt Clusters: Metal–Support Interaction versus Surface Hydride
Mager‐Maury, C., Bonnard, G., Chizallet, C., Sautet, P., & Raybaud, P. (2011) · ChemCatChem · doi:10.1002/cctc.201000324 · Cited by 189
Sanchez, S. I., Menard, L. D., Bram, A., Kang, J. H., Small, M. W., Nuzzo, R. G., & Frenkel, A. I. (2009) · Journal of the American Chemical Society · doi:10.1021/ja809182v · Cited by 161
Performance of Cluster Expansions of Coverage-Dependent Adsorption of Atomic Oxygen on Pt(111)
Schmidt, D. J., Chen, W., Wolverton, C. M., & Schneider, W. F. (2011) · Journal of Chemical Theory and Computation · doi:10.1021/ct200659c · Cited by 107
多形CuInC 2 (C=Se,S)カルコゲン化物の振動および結晶特性
Álvarez-García, J., Barcones, B., Pérez-Rodríguez, A., Romano-Rodriguez, A., Morante, J. R., Janotti, A., Wei, S., & Scheer, R. (2005) · Physical Review B · Cited by 77
First-principles theory and microcalorimetry of CO adsorption on the { 211 } surfaces of Pt and Ni
Karmazyn, A. D., Fiorin, V., Jenkins, S. J., et al. (2003) · Surface Science · doi:10.1016/s0039-6028(03)00726-x · Cited by 57
Structures of metal nanoparticles adsorbed on MgO(001). II. Pt and Pd
Goniakowski, J., Jelea, A., Mottet, C., Barcaro, G., Fortunelli, A., Kuntová, Z., Nita, F., Levi, A. C., Rossi, G., & Ferrando, R. (2009) · The Journal of Chemical Physics · doi:10.1063/1.3121307 · Cited by 57
Electronic shell structure and chemisorption on gold nanoparticles
Larsen, A. H., Kleis, J., Thygesen, K. S., Nørskov, J. K., & Jacobsen, K. W. (2011) · Physical Review B · doi:10.1103/physrevb.84.245429 · Cited by 54
Self-citationPetkov, P. S., Petrova, G. P., Vayssilov, G. N., & Rösch, N. (2010) · The Journal of Physical Chemistry C · doi:10.1021/jp1014274 · Cited by 27
High-fidelity direct coherent diffractive imaging of condensed matter
Morgan, A. J., D’Alfonso, A. J., Martin, A. V., Bishop, A. I., Quiney, H. M., & Allen, L. J. (2011) · Physical Review B · doi:10.1103/physrevb.84.144122 · Cited by 27
Cited by
Biaxially strained PtPb/Pt core/shell nanoplate boosts oxygen reduction catalysis
Bu, L., Zhang, N., Guo, S., Zhang, X., Li, J., Yao, J., Wu, T., Lu, G., Ma, J.-Y., Su, D., et al. (2016) · Science · doi:10.1126/science.aah6133 · Cited by 1,642
Towards dense single-atom catalysts for future automotive applications
Beniya, A., & Higashi, S. (2019) · Nature Catalysis · doi:10.1038/s41929-019-0282-y · Cited by 444
Nanocatalysis: size- and shape-dependent chemisorption and catalytic reactivity
Roldan Cuenya, B., & Behafarid, F. (2015) · Surface Science Reports · doi:10.1016/j.surfrep.2015.01.001 · Cited by 388
Wu, Y., Li, X., Wei, Y., Fu, Z., Wei, W., Wu, X., Zhu, Q., & Xu, Q. (2021) · Advanced Materials · doi:10.1002/adma.202006965 · Cited by 378
Approaches for Understanding and Controlling Interfacial Effects in Oxide-Supported Metal Catalysts
Ro, I., Resasco, J., & Christopher, P. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b02071 · Cited by 316
Metadata
- Authors
- Li, L., Larsen, A. H., Romero, N. A., Morozov, V. A., Glinsvad, C., Abild-Pedersen, F., Greeley, J., Jacobsen, K. W., & Nørskov, J. K.
- Venue
- The Journal of Physical Chemistry Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-12-26
- Volume
- 4
- Issue
- 1
- Pages
- 222-226
- ISSN
- 1948-7185 (ISSN-L)
- OpenAlex
- W2084375601
- Cited by
- 309
- References
- 24
- FWCI
- 8.69
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
