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Adsorption Deformation and Structural Transitions in Metal–Organic Frameworks: From the Unit Cell to the Crystal
Abstract
Much attention has recently been focused on soft porous crystals, a fascinating subclass of metal–organic frameworks that behave in a remarkable stimuli-responsive fashion, presenting structural changes of large amplitude in response to guest adsorption, mechanical pressure, or variations in temperature. In this Perspective, we summarize the recently developed thermodynamic and mechanical theoretical models for the understanding of these materials, based on the concepts of adsorption stress and osmotic thermodynamic ensemble. We show how these models provide a coherent picture of adsorption-induced deformation and structural transitions in flexible metal–organic frameworks, all the way from the length scale of the unit cell to that of the full crystal. In particular, we highlight the new perspectives opened by these models, as well as some of the important open questions in the field.
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Cites
Horike, S., Shimomura, S., & Kitagawa, S. (2009) · Nature Chemistry · doi:10.1038/nchem.444 · Cited by 2,486
Tan, J. C., & Cheetham, A. K. (2011) · Chemical Society Reviews · doi:10.1039/c0cs00163e · Cited by 762
Cited by
Water Stability and Adsorption in Metal–Organic Frameworks
Burtch, N. C., Jasuja, H., & Walton, K. S. (2014) · Chemical Reviews · doi:10.1021/cr5002589 · Cited by 2,730
Water adsorption in MOFs: fundamentals and applications
Canivet, J., Fateeva, A., Guo, Y., Coasne, B., & Farrusseng, D. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00078a · Cited by 1,444
Galizia, M., Chi, W. S., Smith, Z. P., Merkel, T. C., Baker, R. W., & Freeman, B. D. (2017) · Macromolecules · doi:10.1021/acs.macromol.7b01718 · Cited by 989
Metal–Organic Frameworks for Water Harvesting from Air
Kalmutzki, M. J., Diercks, C. S., & Yaghi, O. M. (2018) · Advanced Materials · doi:10.1002/adma.201704304 · Cited by 772
Coudert, F.-X. (2015) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b00046 · Cited by 528
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Metadata
- Authors
- Coudert, F.-X., Boutin, A., Fuchs, A. H., & Neimark, A. V.
- Venue
- The Journal of Physical Chemistry Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-09-13
- Volume
- 4
- Issue
- 19
- Pages
- 3198-3205
- ISSN
- 1948-7185 (ISSN-L)
- OpenAlex
- W2058095943
- Cited by
- 190
- References
- 2
- FWCI
- 8.48
- Type
- journal article
- Language
- en
- Open access
- closed
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