The DOI matches its Crossref record; 30 of the 30 references it cites were found in a registry or an index.
Pt-Based Core–Shell Catalyst Architectures for Oxygen Fuel Cell Electrodes
Abstract
Pt-based core–shell nanoparticles have emerged as a promising generation of highly active electrocatalysts to accelerate the sluggish kinetics of oxygen reduction reaction (ORR) in fuel cell systems. Their electronic and structural properties can be easily tailored by modifying the Pt shell thickness, core composition, diameter, and shape; this results in significant improvements of activity and durability over state-of-the-art pure Pt catalysts. Prompted by the relevance of efficient and robust ORR catalysts for electrochemical energy conversion, this Perspective reviews several concepts and selected recent developments in the exploration of the structure and composition of core–shell nanoparticles. Addressing current achievements and challenges in the preparation as well as microscopic and spectroscopic characterization of core–shell nanocatalysts, a concise account of our understanding is provided on how the surface and subsurface structure of multimetallic core–shell nanoparticles affect their reactivity. Finally, perspectives for the large-scale implementation of core–shell catalysts in polymer exchange membrane fuel cells are discussed.
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Cites
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Cited by
Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions
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Recent Advances in Electrocatalysts for Oxygen Reduction Reaction
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Recent advancements in Pt and Pt-free catalysts for oxygen reduction reaction
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Carbon as catalyst and support for electrochemical energy conversion
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Self-citation
Metadata
- Authors
- Oezaslan, M., Hasché, F., & Strasser, P.
- Venue
- The Journal of Physical Chemistry Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-09-18
- Volume
- 4
- Issue
- 19
- Pages
- 3273-3291
- ISSN
- 1948-7185 (ISSN-L)
- OpenAlex
- W2327895588
- Cited by
- 391
- References
- 30
- FWCI
- 13.10
- Type
- journal article
- Language
- en
- Open access
- closed
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- Oezaslan, M., Hasché, F., & Strasser, P. (2013). Pt-Based Core–Shell Catalyst Architectures for Oxygen Fuel Cell Electrodes. The Journal of Physical Chemistry Letters. https://doi.org/10.1021/jz4014135
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