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Water Sorption on Mesoporous Aluminosilicate MCM-41
Abstract
Characterization of the interaction of water with the highly ordered mesoporous solid MCM-41 (pore diameter -2.5 nm) is undertaken with the aid of several techniques (adsorption gravimetry, X-ray diffraction, Fourier transform infrared spectroscopy, and controlled rate-evolved gas analysis). The relatively complex water-MCM-41 interactions are characterized by a type V isotherm indicating an initial repulsive character followed by a capillary condensation step of the adsorbate. This highlights both hydrophobic and hydrophilic properties of this potential model mesoporous adsorbent.
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Citations
Cited by
Ciesla, U., & Schüth, F. (1999) · Microporous and Mesoporous Materials · doi:10.1016/s1387-1811(98)00249-2 · Cited by 1,084
Advances in Homogeneous and Heterogeneous Catalytic Asymmetric Epoxidation
Xia, Q.-H., Ge, H.-Q., Ye, C.-P., Liu, Z.-M., & Su, K.-X. (2005) · Chemical Reviews · doi:10.1021/cr0406458 · Cited by 983
Comprehensive Study of Surface Chemistry of MCM-41 Using29Si CP/MAS NMR, FTIR, Pyridine-TPD, and TGA
Zhao, X. S., Lu, G. Q., Whittaker, A. K., Millar, G. J., & Zhu, H. Y. (1997) · The Journal of Physical Chemistry B · doi:10.1021/jp971366+ · Cited by 708
Advances in Mesoporous Molecular Sieve MCM-41
Zhao, X. S., Lu, G. Q. (., & Millar, G. J. (1996) · Industrial & Engineering Chemistry Research · doi:10.1021/ie950702a · Cited by 593
Selective Adsorbents from Ordered Mesoporous Silica
Ho, K. Y., McKay, G., & Yeung, K. L. (2003) · Langmuir · doi:10.1021/la0267084 · Cited by 366
Metadata
- Authors
- Llewellyn, P. L., Schueth, F., Grillet, Y., Rouquerol, F., Rouquerol, J., & Unger, K. K.
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 1995-02
- Volume
- 11
- Issue
- 2
- Pages
- 574-577
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W1973449851
- Cited by
- 189
- References
- 0
- FWCI
- 12.57
- Type
- journal article
- Language
- en
- Open access
- closed
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- Llewellyn, P. L., Schueth, F., Grillet, Y., Rouquerol, F., Rouquerol, J., & Unger, K. K. (1995). Water Sorption on Mesoporous Aluminosilicate MCM-41. Langmuir. https://doi.org/10.1021/la00002a036
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