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Mixed Silver/Gold Colloids: A Study of Their Formation, Morphology, and Surface-Enhanced Raman Activity
Abstract
Ag-coated Au and Au-coated Ag colloidal particles were prepared by deposition of Ag or Au through chemical reduction on Au or Ag colloids, respectively. Different amounts of the depositing metal were employed in order to obtain different compositions of the Au 100 - x Ag x and Ag 100 - y Au y resulting particles. The obtained colloids were characterized by UV−vis spectroscopy and transmission electron microscopy. A different formation mechanism was deduced for the different mixed colloids obtained by this procedure. Moreover, the activity of these colloids in surface-enhanced Raman spectroscopy (SERS), that is, the SERS enhancement factor, was checked by using pyridine as an adsorbate probe. The SERS excitation profiles for each colloid were investigated in order to obtain information about the activity of these substrates at different excitation wavelengths as well as to estimate the relative exposed area of each metal in every composite colloid.
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Citations
Cites
Beiträge zur Optik trüber Medien, speziell kolloidaler Metallösungen
Mie, G. (1908) · Annalen der Physik · doi:10.1002/andp.19083300302 · Cited by 11,537
Cited by
Tailoring Surface Plasmons through the Morphology and Assembly of Metal Nanoparticles
Liz-Marzán, L. M. (2006) · Langmuir · doi:10.1021/la0513353 · Cited by 1,645
Nanostructured Surfaces and Assemblies as SERS Media
Ko, H., Singamaneni, S., & Tsukruk, V. V. (2008) · Small · doi:10.1002/smll.200800337 · Cited by 786
DNA-Modified Core−Shell Ag/Au Nanoparticles
Cao, Jin, R., & Mirkin, C. A. (2001) · Journal of the American Chemical Society · doi:10.1021/ja011342n · Cited by 676
Surface‐enhanced Raman scattering spectroscopy via gold nanostars
Nalbant Esenturk, E., & Hight Walker, A. R. (2009) · Journal of Raman Spectroscopy · doi:10.1002/jrs.2084 · Cited by 295
Metadata
- Authors
- Rivas, L., Sanchez-Cortes, S., García-Ramos, J. V., & Morcillo, G.
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 2000-11-10
- Volume
- 16
- Issue
- 25
- Pages
- 9722-9728
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W2092957348
- Cited by
- 253
- References
- 1
- FWCI
- 3.20
- Type
- journal article
- Language
- en
- Open access
- closed
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