The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Photocatalytic Transformation of Organic Compounds in the Presence of Inorganic Ions. 2. Competitive Reactions of Phenol and Alcohols on a Titanium Dioxide−Fluoride System
Abstract
The photocatalytic transformation of phenol has been investigated on naked TiO 2 and on TiO 2 /F (0.01 M F - ) at pH 3.6 in the presence of different alcohols ( tert -butyl alcohol, 2-propanol, and furfuryl alcohol). On the basis of a detailed kinetic analysis and the time evolution of the intermediates, it is suggested that on naked TiO 2 the oxidation of phenol proceeds for 90% through the reaction with surficial bound hydroxyl radical, the remaining 10% via a direct interaction with the holes. On TiO 2 /F the reaction proceeds almost entirely via homogeneous hydroxyl radicals because of the unavailability of surface-bound hydroxyl in the presence of fluoride ions. The use of alcohols as a diagnostic tool for the analysis of the photocatalytic mechanism is discussed.
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Cites
Environmental applications of semiconductor photocatalysis
Hoffmann, M. R., Martin, S. T., Choi, W., & Bahnemann, D. W. (1995) · Chemical Reviews · doi:10.1021/cr00033a004 · Cited by 18,495
Buxton, G. V., Greenstock, C. L., Helman, W. P., & Ross, A. B. (1988) · Journal of Physical and Chemical Reference Data · doi:10.1063/1.555805 · Cited by 12,332
Cited by
Yin, M., Li, Z., Kou, J., & Zou, Z. (2009) · Environmental Science & Technology · doi:10.1021/es902011h · Cited by 490
Chen, Y., Yang, S., Wang, K., & Lou, L. (2005) · Journal of Photochemistry and Photobiology A: Chemistry · doi:10.1016/j.jphotochem.2004.11.006 · Cited by 466
Yu, J., Liu, S., & Yu, H. (2007) · Journal of Catalysis · doi:10.1016/j.jcat.2007.03.032 · Cited by 371
Metadata
- Authors
- Minero, C., Mariella, G., Maurino, V., Vione, D., & Pelizzetti, E.
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 2000-09-19
- Volume
- 16
- Issue
- 23
- Pages
- 8964-8972
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W2025449499
- Cited by
- 410
- References
- 2
- FWCI
- 8.81
- Type
- journal article
- Language
- en
- Open access
- closed
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