The DOI matches its Crossref record.
Surface-Initiated Polymerizations in Aqueous Media: Effect of Initiator Density
Abstract
We report the first systematic study of initiator density on surface-initiated polymerizations. We used mixed monolayers comprising of undecanethiol and ω-mercaptoundecyl bromoisobutyrate ( 1 ) to initiate the controlled radical polymerization of methyl methacrylate (MMA) and glycidyl methacrylate (GMA) from gold. We found that SAMs composed of 10% and 50% of initiator 1 grow PMMA brushes to approximately 1/10 and 1/2 the thickness of polymer brushes grafted from SAMs comprising 100% 1 . We did not find a clear maximum initiator density, beyond which no further increase in polymer brush thickness is observed. We show that the initiator density at the start of the polymerization determines the ultimate “footprint” and hence density of polymer molecules in polymer brushes.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Barbey, R., Lavanant, L., Paripovic, D., Schüwer, N., Sugnaux, C., Tugulu, S., & Klok, H.-A. (2009) · Chemical Reviews · doi:10.1021/cr900045a · Cited by 1,753
Zoppe, J. O., Ataman, N. C., Mocny, P., Wang, J., Moraes, J., & Klok, H.-A. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00314 · Cited by 1,046
Murata, H., Koepsel, R. R., Matyjaszewski, K., & Russell, A. J. (2007) · Biomaterials · doi:10.1016/j.biomaterials.2007.06.012 · Cited by 722
Synthesis of Polymer Brushes Using Atom Transfer Radical Polymerization
Pyun, J., Kowalewski, T., & Matyjaszewski, K. (2003) · Macromolecular Rapid Communications · doi:10.1002/marc.200300078 · Cited by 686
Tsujii, Y., Ohno, K., Yamamoto, S., Goto, A., & Fukuda, T. (2006) · Advances in Polymer Science · doi:10.1007/12_063 · Cited by 621
Rong, M. Z., Zhang, M. Q., & Ruan, W. H. (2006) · Materials Science and Technology · doi:10.1179/174328406x101247 · Cited by 558
Wong, I., & Ho, C.-M. (2009) · Microfluidics and Nanofluidics · doi:10.1007/s10404-009-0443-4 · Cited by 531
Modeling and theoretical development in controlled radical polymerization
Mastan, E., Li, X., & Zhu, S. (2015) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2014.12.003 · Cited by 131
Advincula, R., Zhou, Q., Park, M., Wang, S., Mays, J., Sakellariou, G., Pispas, S., & Hadjichristidis, N. (2002) · Langmuir · doi:10.1021/la025962t · Cited by 123
Metadata
- Authors
- Jones, D. M., Brown, A. A., & Huck, W. T. S.
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-01-26
- Volume
- 18
- Issue
- 4
- Pages
- 1265-1269
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W1970338858
- Cited by
- 470
- References
- 0
- FWCI
- 15.89
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
