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Seeded Growth of Submicron Au Colloids with Quadrupole Plasmon Resonance Modes
Abstract
A modified seeded growth process has been used for the controlled synthesis of quasispherical, CTAB-stabilized gold nanoparticles from 12 up to 180 nm with narrow size distributions. The UV-visible spectra of the aqueous colloids show distinct bands corresponding to dipole and quadrupole plasmon modes, for diameters above 100 nm, in close agreement with predictions based on Mie theory. The assignment of the modes is demonstrated by calculation of near field enhancement maps based on the boundary element method. Apart from other applications, since absorption is drastically reduced above 600 nm, while scattering is largely increased, these particles open new possibilities for construction of highly efficient photonic structures.
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Cited by
Gold Nanomaterials at Work in Biomedicine
Yang, X., Yang, M., Pang, B., Vara, M., & Xia, Y. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00193 · Cited by 1,162
State of the art in gold nanoparticle synthesis
Zhao, P., Li, N., & Astruc, D. (2013) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2012.09.002 · Cited by 964
Colloidal Gold and Silver Triangular Nanoprisms
Millstone, J. E., Hurst, S. J., Métraux, G. S., Cutler, J. I., & Mirkin, C. A. (2009) · Small · doi:10.1002/smll.200801480 · Cited by 895
Synthesis, structure and properties of metal nanoclusters
Wilcoxon, J. P., & Abrams, B. L. (2006) · Chemical Society Reviews · doi:10.1039/b517312b · Cited by 760
Fundamental growth principles of colloidal metal nanoparticles – a new perspective
Polte, J. (2015) · CrystEngComm · doi:10.1039/c5ce01014d · Cited by 746
Metadata
- Authors
- Rodríguez-Fernández, J., Pérez-Juste, J., García de Abajo, F. J., & Liz-Marzán, L. M.
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-06-29
- Volume
- 22
- Issue
- 16
- Pages
- 7007-7010
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W2039557460
- Cited by
- 382
- References
- 0
- FWCI
- 8.75
- Type
- journal article
- Language
- en
- Open access
- closed
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- Rodríguez-Fernández, J., Pérez-Juste, J., García de Abajo, F. J., & Liz-Marzán, L. M. (2006). Seeded Growth of Submicron Au Colloids with Quadrupole Plasmon Resonance Modes. Langmuir. https://doi.org/10.1021/la060990n
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