The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Surface Tensions, Surface Potentials, and the Hofmeister Series of Electrolyte Solutions
Open accessAbstract
A theory is presented which allows us to accurately calculate the surface tensions and the surface potentials of electrolyte solutions. Both the ionic hydration and the polarizability are taken into account. We find a good correlation between the Jones-Dole viscosity B coefficient and the ionic hydration near the air-water interface. The kosmotropic anions such as fluoride, iodate, sulfate, and carbonate are found to be strongly hydrated and are repelled from the interface. The chaotropic anions such as perchlorate, iodide, chlorate, and bromide are found to be significantly adsorbed to the interface. Chloride and bromate anions become weakly hydrated in the interfacial region. The sequence of surface tensions and surface potentials is found to follow the Hofmeister ordering. The theory quantitatively accounts for the surface tensions of 10 sodium salts for which there is experimental data.
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Citations
Cites
Phenomenological Theory of Ion Solvation. Effective Radii of Hydrated Ions
Nightingale, E. R. (1959) · The Journal of Physical Chemistry · doi:10.1021/j150579a011 · Cited by 3,505
Viscosity B-Coefficients of Ions in Solution
Jenkins, H. D. B., & Marcus, Y. (1995) · Chemical Reviews · doi:10.1021/cr00040a004 · Cited by 715
Cited by
Understanding specific ion effects and the Hofmeister series
Gregory, K. P., Elliott, G. R., Robertson, H., Kumar, A., Wanless, E. J., Webber, G. B., Craig, V. S. J., Andersson, G. G., & Page, A. J. (2022) · Physical Chemistry Chemical Physics · doi:10.1039/d2cp00847e · Cited by 462
Raman spectroscopy of alkali halide hydration: hydrogen bond relaxation and polarization
Gong, Y., Zhou, Y., Wu, H., Wu, D., Huang, Y., & Sun, C. Q. (2016) · Journal of Raman Spectroscopy · doi:10.1002/jrs.4963 · Cited by 40
Metadata
- Authors
- dos Santos, A. P., Diehl, A., & Levin, Y.
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-04-02
- Volume
- 26
- Issue
- 13
- Pages
- 10778-10783
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W2017092746
- Cited by
- 210
- References
- 2
- FWCI
- 9.16
- Type
- journal article
- Language
- en
- Open access
- green
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