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Thermosensitive Pickering Emulsion Stabilized by Poly(N-isopropylacrylamide)-Carrying Particles
Abstract
Poly(N-isopropylacrylamide) (PNIPAM)-carrying particles were characterized as thermosensitive Pickering emulsifiers. Emulsions were prepared from various oils, such as heptane, hexadecane, trichloroethylene, and toluene, with PNIPAM-carrying particles. PNIPAM-carrying particles preferentially formed oil-in-water (O/W)-type emulsions with a variety of oils. All the emulsions stabilized by PNIPAM-carrying particles were stable for more than 3 months as long as they were stored at room temperature. However, when the emulsions were heated from room temperature to 40 degrees C, at which point the PNIPAM layer caused a coil-to-globule transition, phase separation occurred. Thus, by using thermosensitive PNIPAM-carrying particles as emulsifiers, the stability of the Pickering emulsions could be controlled by a slight change in temperature.
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Cited by
Emulsions stabilized with solid nanoparticles: Pickering emulsions
Chevalier, Y., & Bolzinger, M.-A. (2013) · Colloids and Surfaces A: Physicochemical and Engineering Aspects · doi:10.1016/j.colsurfa.2013.02.054 · Cited by 1,765
Zoppe, J. O., Venditti, R. A., & Rojas, O. J. (2012) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2011.12.011 · Cited by 362
Tang, J., Lee, M. F. X., Zhang, W., Zhao, B., Berry, R. M., & Tam, K. C. (2014) · Biomacromolecules · doi:10.1021/bm500663w · Cited by 309
Kargar, M., Fayazmanesh, K., Alavi, M., Spyropoulos, F., & Norton, I. T. (2012) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2011.09.073 · Cited by 306
Liu, H., Wang, C., Zou, S., Wei, Z., & Tong, Z. (2012) · Langmuir · doi:10.1021/la3021113 · Cited by 284
Metadata
- Authors
- Tsuji, S., & Kawaguchi, H.
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-03-07
- Volume
- 24
- Issue
- 7
- Pages
- 3300-3305
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W1982074883
- Cited by
- 205
- References
- 0
- FWCI
- 5.39
- Type
- journal article
- Language
- en
- Open access
- closed
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- Tsuji, S., & Kawaguchi, H. (2008). Thermosensitive Pickering Emulsion Stabilized by Poly(N-isopropylacrylamide)-Carrying Particles. Langmuir. https://doi.org/10.1021/la701780g
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